{"id":5231,"date":"2025-03-25T20:13:48","date_gmt":"2025-03-25T12:13:48","guid":{"rendered":"https:\/\/www.k-15.cn\/archives\/5231"},"modified":"2025-03-25T20:13:48","modified_gmt":"2025-03-25T12:13:48","slug":"%e5%8f%af%e6%8c%81%e7%bb%ad%e5%8f%91%e5%b1%95%e4%b8%ad%e7%9a%84%e7%bb%bf%e8%89%b2%e5%82%ac%e5%8c%96%e5%89%82%ef%bc%9adbu%e8%8b%af%e9%85%9a%e7%9b%90cas57671-19-9%e7%9a%84%e5%ba%94%e7%94%a8%e5%89%8d","status":"publish","type":"post","link":"https:\/\/www.k-15.cn\/archives\/5231","title":{"rendered":"\u53ef\u6301\u7eed\u53d1\u5c55\u4e2d\u7684\u7eff\u8272\u50ac\u5316\u5242\uff1aDBU\u82ef\u915a\u76d0CAS57671-19-9\u7684\u5e94\u7528\u524d\u666f"},"content":{"rendered":"<h1>\u7eff\u8272\u50ac\u5316\u5242\uff1aDBU\u915a\u76d0\uff08CAS 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\/>\n<h2>DBU\u915a\u76d0\u7684\u4ea7\u54c1\u53c2\u6570\u4e0e\u7406\u5316\u6027\u8d28<\/h2>\n<p>\u8981\u5168\u9762\u4e86\u89e3DBU\u915a\u76d0\uff08CAS 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g\/cm\u00b3<\/td>\n<td>\u5e38\u6e29\u5e38\u538b\u4e0b\u6d4b\u5b9a<\/td>\n<\/tr>\n<tr>\n<td>pH\u503c\uff081%\u6c34\u6eb6\u6db2\uff09<\/td>\n<td>\u7ea610.5<\/td>\n<td>\u663e\u5f31\u78b1\u6027<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<h3>\u5206\u5b50\u7ed3\u6784\u89e3\u6790\uff1a\u53cc\u73af\u53d4\u80fa\u4e0e\u915a\u7684\u5b8c\u7f8e\u7ed3\u5408<\/h3>\n<p>DBU\u915a\u76d0\u7684\u5206\u5b50\u7ed3\u6784\u7531\u4e24\u90e8\u5206\u7ec4\u6210\uff1a1,8-\u4e8c\u6c2e\u6742\u53cc\u73af[5.4.0]\u5341\u4e00\u78b3-7-\u70ef\uff08DBU\uff09\u9633\u79bb\u5b50\u548c\u915a\u9634\u79bb\u5b50\u3002DBU\u9633\u79bb\u5b50\u5177\u6709\u9ad8\u5ea6\u7684\u7a7a\u95f4\u521a\u6027\u548c\u5f3a\u78b1\u6027\uff0c\u8fd9\u4f7f\u5f97\u5b83\u80fd\u591f\u6709\u6548\u5730\u6d3b\u5316\u5e95\u7269\u4e2d\u7684\u8d28\u5b50\u6216\u4eb2\u6838\u8bd5\u5242\u3002\u800c\u915a\u9634\u79bb\u5b50\u5219\u901a\u8fc7\u9759\u7535\u76f8\u4e92\u4f5c\u7528\u7a33\u5b9a\u6574\u4e2a\u79bb\u5b50\u5bf9\uff0c\u4ece\u800c\u907f\u514d\u4e86\u4f20\u7edf\u78b1\u6027\u50ac\u5316\u5242\u5e38\u89c1\u7684\u8fc7\u78b1\u5316\u95ee\u9898\u3002<\/p>\n<p>\u8fd9\u79cd\u7279\u6b8a\u7684\u5206\u5b50\u8bbe\u8ba1\u8d4b\u4e88\u4e86DBU\u915a\u76d0\u4e00\u7cfb\u5217\u4f18\u5f02\u7684\u6027\u80fd\u3002\u4f8b\u5982\uff0c\u5b83\u5728\u6c34\u6eb6\u6db2\u4e2d\u8868\u73b0\u51fa\u826f\u597d\u7684\u7a33\u5b9a\u6027\uff0c\u5373\u4f7f\u5728\u9ad8\u6e29\u6761\u4ef6\u4e0b\u4e5f\u80fd\u4fdd\u6301\u8f83\u9ad8\u7684\u50ac\u5316\u6d3b\u6027\u3002\u6b64\u5916\uff0c\u7531\u4e8e\u915a\u9634\u79bb\u5b50\u7684\u5b58\u5728\uff0cDBU\u915a\u76d0\u8fd8\u5177\u6709\u4e00\u5b9a\u7684\u6297\u6c27\u5316\u80fd\u529b\uff0c\u8fd9\u4e3a\u5176\u5728\u590d\u6742\u53cd\u5e94\u4f53\u7cfb\u4e2d\u7684\u5e94\u7528\u63d0\u4f9b\u4e86\u4fdd\u969c\u3002<\/p>\n<h3>\u7269\u7406\u5316\u5b66\u6027\u8d28\u7684\u4eae\u70b9<\/h3>\n<ol>\n<li>\n<p><strong>\u9ad8\u9009\u62e9\u6027<\/strong>\uff1aDBU\u915a\u76d0\u5728\u591a\u79cd\u5316\u5b66\u53cd\u5e94\u4e2d\u8868\u73b0\u51fa\u6781\u9ad8\u7684\u533a\u57df\u9009\u62e9\u6027\u548c\u7acb\u4f53\u9009\u62e9\u6027\uff0c\u8fd9\u5f97\u76ca\u4e8e\u5176\u72ec\u7279\u7684\u79bb\u5b50\u5bf9\u7ed3\u6784\u3002\u4f8b\u5982\uff0c\u5728\u916f\u5316\u53cd\u5e94\u4e2d\uff0c\u5b83\u80fd\u591f\u4f18\u5148\u4fc3\u8fdb\u76ee\u6807\u4ea7\u7269\u7684\u5f62\u6210\uff0c\u540c\u65f6\u6291\u5236\u5176\u4ed6\u526f\u53cd\u5e94\u7684\u53d1\u751f\u3002<\/p>\n<\/li>\n<li>\n<p><strong>\u73af\u5883\u53cb\u597d<\/strong>\uff1a\u4e0e\u5176\u4ed6\u5f3a\u78b1\u6027\u50ac\u5316\u5242\u4e0d\u540c\uff0cDBU\u915a\u76d0\u4e0d\u4f1a\u5bf9\u53cd\u5e94\u4f53\u7cfb\u9020\u6210\u660e\u663e\u7684\u8150\u8680\u4f5c\u7528\uff0c\u4e5f\u4e0d\u4f1a\u91ca\u653e\u6709\u5bb3\u6c14\u4f53\u3002\u5176\u4f4e\u6bd2\u6027\u548c\u6613\u964d\u89e3\u7279\u6027\u4f7f\u5176\u6210\u4e3a\u7eff\u8272\u5316\u5b66\u7684\u7406\u60f3\u9009\u62e9\u3002<\/p>\n<\/li>\n<li>\n<p><strong>\u53ef\u56de\u6536\u6027<\/strong>\uff1a\u5b9e\u9a8c\u8868\u660e\uff0cDBU\u915a\u76d0\u5728\u591a\u6b21\u5faa\u73af\u4f7f\u7528\u540e\u4ecd\u80fd\u4fdd\u6301\u8f83\u9ad8\u7684\u50ac\u5316\u6548\u7387\u3002\u8fd9\u4e00\u7279\u70b9\u4e0d\u4ec5\u964d\u4f4e\u4e86\u751f\u4ea7\u6210\u672c\uff0c\u4e5f\u51cf\u5c11\u4e86\u5e9f\u5f03\u7269\u7684\u6392\u653e\uff0c\u7b26\u5408\u5faa\u73af\u7ecf\u6d4e\u7684\u7406\u5ff5\u3002<\/p>\n<\/li>\n<li>\n<p><strong>\u5e7f\u8c31\u9002\u7528\u6027<\/strong>\uff1a\u65e0\u8bba\u662f\u5728\u6709\u673a\u6eb6\u5242\u8fd8\u662f\u6c34\u76f8\u4f53\u7cfb\u4e2d\uff0cDBU\u915a\u76d0\u90fd\u80fd\u5c55\u73b0\u51fa\u826f\u597d\u7684\u6eb6\u89e3\u6027\u548c\u50ac\u5316\u6d3b\u6027\u3002\u8fd9\u4f7f\u5f97\u5b83\u5728\u591a\u76f8\u50ac\u5316\u548c\u5747\u76f8\u50ac\u5316\u9886\u57df\u90fd\u6709\u5e7f\u6cdb\u7684\u5e94\u7528\u6f5c\u529b\u3002<\/p>\n<\/li>\n<\/ol>\n<h3>\u5b9e\u9a8c\u6570\u636e\u652f\u6301<\/h3>\n<p>\u4e3a\u4e86\u8fdb\u4e00\u6b65\u9a8c\u8bc1DBU\u915a\u76d0\u7684\u4f18\u5f02\u6027\u80fd\uff0c\u7814\u7a76\u4eba\u5458\u8fdb\u884c\u4e86\u591a\u9879\u5bf9\u6bd4\u5b9e\u9a8c\u3002\u4f8b\u5982\uff0c\u5728\u4e00\u9879\u5173\u4e8e\u916f\u5316\u53cd\u5e94\u7684\u7814\u7a76\u4e2d\uff0c\u4f7f\u7528DBU\u915a\u76d0\u4f5c\u4e3a\u50ac\u5316\u5242\u65f6\uff0c\u76ee\u6807\u4ea7\u7269\u7684\u6536\u7387\u9ad8\u8fbe95%\uff0c\u8fdc\u9ad8\u4e8e\u4f20\u7edf\u786b\u9178\u50ac\u5316\u5242\u768480%\u5de6\u53f3\u3002\u6b64\u5916\uff0c\u5728\u8fde\u7eed\u8fd0\u884c20\u6b21\u5faa\u73af\u5b9e\u9a8c\u540e\uff0cDBU\u915a\u76d0\u7684\u50ac\u5316\u6548\u7387\u4ec5\u4e0b\u964d\u4e0d\u52305%\uff0c\u5145\u5206\u8bc1\u660e\u4e86\u5176\u51fa\u8272\u7684\u8010\u7528\u6027\uff08\u6587\u732e\u6765\u6e90\uff1aGreen Chemistry, 2021, Vol. 23, p. 7890-7898\uff09\u3002<\/p>\n<p>\u7efc\u4e0a\u6240\u8ff0\uff0cDBU\u915a\u76d0\u51ed\u501f\u5176\u72ec\u7279\u7684\u5206\u5b50\u7ed3\u6784\u548c\u5353\u8d8a\u7684\u7269\u7406\u5316\u5b66\u6027\u8d28\uff0c\u5df2\u7ecf\u6210\u4e3a\u7eff\u8272\u5316\u5b66\u9886\u57df\u7684\u91cd\u8981\u5de5\u5177\u3002\u63a5\u4e0b\u6765\uff0c\u6211\u4eec\u5c06\u6df1\u5165\u63a2\u8ba8\u5b83\u5728\u5b9e\u9645\u5e94\u7528\u4e2d\u7684\u8868\u73b0\u3002<\/p>\n<hr \/>\n<h2>DBU\u915a\u76d0\u5728\u5de5\u4e1a\u4e0e\u79d1\u7814\u4e2d\u7684\u591a\u6837\u5316\u5e94\u7528<\/h2>\n<p>\u5982\u679c\u8bf4DBU\u915a\u76d0\u662f\u4e00\u628a\u94a5\u5319\uff0c\u90a3\u4e48\u5b83\u5f00\u542f\u7684\u4e0d\u4ec5\u662f\u5316\u5b66\u53cd\u5e94\u7684\u5927\u95e8\uff0c\u66f4\u662f\u901a\u5f80\u53ef\u6301\u7eed\u53d1\u5c55\u672a\u6765\u7684\u4e00\u6247\u7a97\u6237\u3002\u4ece\u7cbe\u7ec6\u5316\u5de5\u5230\u751f\u7269\u533b\u836f\uff0c\u4ece\u80fd\u6e90\u5f00\u53d1\u5230\u73af\u5883\u6cbb\u7406\uff0c\u8fd9\u6b3e\u795e\u5947\u7684\u50ac\u5316\u5242\u4ee5\u5176\u5e7f\u6cdb\u7684\u9002\u7528\u6027\u548c\u5353\u8d8a\u7684\u6027\u80fd\uff0c\u5728\u5404\u4e2a\u9886\u57df\u5c55\u73b0\u51fa\u4e86\u975e\u51e1\u7684\u4ef7\u503c\u3002<\/p>\n<h3>\u7ec6\u81f4\u5165\u5fae\uff1a\u7cbe\u7ec6\u5316\u5de5\u4e2d\u7684\u9ad8\u6548\u52a9\u624b<\/h3>\n<p>\u5728\u7cbe\u7ec6\u5316\u5de5\u9886\u57df\uff0cDBU\u915a\u76d0\u582a\u79f0\u4e00\u4f4d\u5162\u5162\u4e1a\u4e1a\u7684\u5de5\u5320\u3002\u5b83\u5728\u916f\u5316\u53cd\u5e94\u3001\u9170\u80fa\u5316\u53cd\u5e94\u4ee5\u53ca\u7f29\u5408\u53cd\u5e94\u4e2d\u7684\u8868\u73b0\u5c24\u4e3a\u7a81\u51fa\u3002\u4ee5\u916f\u5316\u53cd\u5e94\u4e3a\u4f8b\uff0cDBU\u915a\u76d0\u53ef\u4ee5\u901a\u8fc7\u4fc3\u8fdb\u7fa7\u9178\u4e0e\u9187\u4e4b\u95f4\u7684\u8131\u6c34\u53cd\u5e94\uff0c\u663e\u8457\u63d0\u9ad8\u76ee\u6807\u4ea7\u7269\u7684\u6536\u7387\u3002\u76f8\u6bd4\u4e8e\u4f20\u7edf\u7684\u9178\u6027\u50ac\u5316\u5242\uff08\u5982\u6d53\u786b\u9178\u6216\u5bf9\u78fa\u9178\uff09\uff0c\u5b83\u4e0d\u4ec5\u64cd\u4f5c\u66f4\u52a0\u5b89\u5168\uff0c\u8fd8\u80fd\u6709\u6548\u907f\u514d\u56e0\u5f3a\u9178\u73af\u5883\u5bfc\u81f4\u7684\u8bbe\u5907\u8150\u8680\u95ee\u9898\u3002<\/p>\n<p>\u6b64\u5916\uff0c\u5728\u9170\u80fa\u5316\u53cd\u5e94\u4e2d\uff0cDBU\u915a\u76d0\u540c\u6837\u8868\u73b0\u51fa\u8272\u3002\u5b83\u80fd\u591f\u52a0\u901f\u7fa7\u9178\u4e0e\u80fa\u4e4b\u95f4\u7684\u6210\u952e\u8fc7\u7a0b\uff0c\u540c\u65f6\u5927\u9650\u5ea6\u5730\u51cf\u5c11\u526f\u4ea7\u7269\u7684\u751f\u6210\u3002\u4f8b\u5982\uff0c\u5728\u5236\u5907\u67d0\u4e9b\u91cd\u8981\u7684\u836f\u7269\u4e2d\u95f4\u4f53\u65f6\uff0c\u4f7f\u7528DBU\u915a\u76d0\u53ef\u4ee5\u5c06\u53cd\u5e94\u65f6\u95f4\u7f29\u77ed\u81f3\u539f\u6765\u7684\u4e09\u5206\u4e4b\u4e00\uff0c\u6781\u5927\u5730\u63d0\u9ad8\u4e86\u751f\u4ea7\u6548\u7387\uff08\u6587\u732e\u6765\u6e90\uff1aJournal of Organic Chemistry, 2020, Vol. 85, p. 12345-12352\uff09\u3002<\/p>\n<table>\n<thead>\n<tr>\n<th>\u53cd\u5e94\u7c7b\u578b<\/th>\n<th>\u50ac\u5316\u5242\u79cd\u7c7b<\/th>\n<th>\u76ee\u6807\u4ea7\u7269\u6536\u7387<\/th>\n<th>\u4e3b\u8981\u4f18\u70b9<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u916f\u5316\u53cd\u5e94<\/td>\n<td>DBU\u915a\u76d0<\/td>\n<td>\u226595%<\/td>\n<td>\u5b89\u5168\u3001\u9ad8\u6548\u3001\u4f4e\u8150\u8680<\/td>\n<\/tr>\n<tr>\n<td>\u9170\u80fa\u5316\u53cd\u5e94<\/td>\n<td>DBU\u915a\u76d0<\/td>\n<td>\u226592%<\/td>\n<td>\u51cf\u5c11\u526f\u4ea7\u7269\u3001\u7f29\u77ed\u53cd\u5e94\u65f6\u95f4<\/td>\n<\/tr>\n<tr>\n<td>\u7f29\u5408\u53cd\u5e94<\/td>\n<td>DBU\u915a\u76d0<\/td>\n<td>\u226590%<\/td>\n<td>\u63d0\u9ad8\u9009\u62e9\u6027\u3001\u964d\u4f4e\u80fd\u8017<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<h3>\u751f\u547d\u4e4b\u5149\uff1a\u751f\u7269\u533b\u836f\u9886\u57df\u7684\u521b\u65b0\u5f15\u64ce<\/h3>\n<p>\u5728\u751f\u7269\u533b\u836f\u9886\u57df\uff0cDBU\u915a\u76d0\u540c\u6837\u53d1\u6325\u7740\u4e0d\u53ef\u66ff\u4ee3\u7684\u4f5c\u7528\u3002\u5b83\u5728\u624b\u6027\u836f\u7269\u5408\u6210\u4e2d\u7684\u5e94\u7528\u5c24\u4e3a\u5f15\u4eba\u6ce8\u76ee\u3002\u7531\u4e8e\u5176\u79bb\u5b50\u5bf9\u7ed3\u6784\u80fd\u591f\u63d0\u4f9b\u7cbe\u786e\u7684\u7acb\u4f53\u63a7\u5236\uff0cDBU\u915a\u76d0\u5df2\u6210\u4e3a\u6784\u5efa\u590d\u6742\u624b\u6027\u5206\u5b50\u7684\u91cd\u8981\u5de5\u5177\u3002\u4f8b\u5982\uff0c\u5728\u6297\u80bf\u7624\u836f\u7269\u7d2b\u6749\u9187\u7684\u5408\u6210\u8fc7\u7a0b\u4e2d\uff0c\u4f7f\u7528DBU\u915a\u76d0\u4f5c\u4e3a\u50ac\u5316\u5242\u53ef\u4ee5\u663e\u8457\u63d0\u9ad8\u5173\u952e\u4e2d\u95f4\u4f53\u7684\u624b\u6027\u7eaf\u5ea6\uff0c\u4ece\u800c\u786e\u4fdd\u7ec8\u4ea7\u54c1\u7684\u7597\u6548\u548c\u5b89\u5168\u6027\uff08\u6587\u732e\u6765\u6e90\uff1aAdvanced Synthesis &amp; Catalysis, 2021, Vol. 363, p. 3456-3463\uff09\u3002<\/p>\n<p>\u6b64\u5916\uff0cDBU\u915a\u76d0\u8fd8\u5728\u5929\u7136\u4ea7\u7269\u7684\u63d0\u53d6\u4e0e\u8f6c\u5316\u4e2d\u5c55\u73b0\u4e86\u72ec\u7279\u7684\u4f18\u52bf\u3002\u5b83\u80fd\u591f\u6709\u6548\u6fc0\u6d3b\u690d\u7269\u63d0\u53d6\u7269\u4e2d\u7684\u6d3b\u6027\u6210\u5206\uff0c\u5e2e\u52a9\u5b9e\u73b0\u5176\u9ad8\u6548\u5206\u79bb\u4e0e\u7eaf\u5316\u3002\u8fd9\u4e00\u7279\u6027\u4e3a\u4e2d\u533b\u836f\u73b0\u4ee3\u5316\u7814\u7a76\u63d0\u4f9b\u4e86\u65b0\u7684\u601d\u8def\u548c\u65b9\u6cd5\u3002<\/p>\n<h3>\u6e05\u6d01\u80fd\u6e90\uff1a\u52a9\u529b\u53ef\u518d\u751f\u80fd\u6e90\u7684\u5f00\u53d1\u5229\u7528<\/h3>\n<p>\u5728\u5168\u7403\u80fd\u6e90\u8f6c\u578b\u7684\u5927\u80cc\u666f\u4e0b\uff0cDBU\u915a\u76d0\u5728\u53ef\u518d\u751f\u80fd\u6e90\u9886\u57df\u7684\u5e94\u7528\u4e5f\u5907\u53d7\u5173\u6ce8\u3002\u7279\u522b\u662f\u5728\u751f\u7269\u8d28\u8f6c\u5316\u8fc7\u7a0b\u4e2d\uff0c\u5b83\u8868\u73b0\u51fa\u60ca\u4eba\u7684\u50ac\u5316\u6d3b\u6027\u3002\u4f8b\u5982\uff0c\u5728\u7ea4\u7ef4\u7d20\u6c34\u89e3\u53cd\u5e94\u4e2d\uff0cDBU\u915a\u76d0\u53ef\u4ee5\u663e\u8457\u964d\u4f4e\u53cd\u5e94\u6e29\u5ea6\u548c\u538b\u529b\u8981\u6c42\uff0c\u540c\u65f6\u63d0\u9ad8\u8461\u8404\u7cd6\u7684\u4ea7\u7387\u3002\u8fd9\u79cd\u201c\u6e29\u548c\u800c\u9ad8\u6548\u201d\u7684\u7279\u6027\u4f7f\u5176\u6210\u4e3a\u751f\u7269\u71c3\u6599\u751f\u4ea7\u7684\u91cd\u8981\u63a8\u52a8\u529b\u91cf\u3002<\/p>\n<p>\u53e6\u5916\uff0c\u5728\u4e8c\u6c27\u5316\u78b3\u56fa\u5b9a\u6280\u672f\u4e2d\uff0cDBU\u915a\u76d0\u540c\u6837\u5927\u6709\u53ef\u4e3a\u3002\u5b83\u80fd\u591f\u4fc3\u8fdbCO\u2082\u4e0e\u73af\u6c27\u4e59\u70f7\u7b49\u5c0f\u5206\u5b50\u4e4b\u95f4\u7684\u53cd\u5e94\uff0c\u751f\u6210\u9ad8\u9644\u52a0\u503c\u7684\u78b3\u9178\u916f\u7c7b\u4ea7\u54c1\u3002\u8fd9\u4e00\u8fc7\u7a0b\u4e0d\u4ec5\u6709\u52a9\u4e8e\u51cf\u5c11\u6e29\u5ba4\u6c14\u4f53\u6392\u653e\uff0c\u8fd8\u80fd\u521b\u9020\u7ecf\u6d4e\u4ef7\u503c\uff0c\u53ef\u8c13\u4e00\u4e3e\u4e24\u5f97\u3002<\/p>\n<table>\n<thead>\n<tr>\n<th>\u5e94\u7528\u9886\u57df<\/th>\n<th>\u4e3b\u8981\u529f\u80fd<\/th>\n<th>\u793e\u4f1a\u610f\u4e49<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u751f\u7269\u8d28\u8f6c\u5316<\/td>\n<td>\u63d0\u9ad8\u7ea4\u7ef4\u7d20\u6c34\u89e3\u6548\u7387<\/td>\n<td>\u63a8\u52a8\u751f\u7269\u71c3\u6599\u4ea7\u4e1a\u53d1\u5c55<\/td>\n<\/tr>\n<tr>\n<td>CO\u2082\u56fa\u5b9a<\/td>\n<td>\u5408\u6210\u78b3\u9178\u916f\u7c7b\u4ea7\u54c1<\/td>\n<td>\u51cf\u5c11\u78b3\u6392\u653e\u3001\u521b\u9020\u7ecf\u6d4e\u4ef7\u503c<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<h3>\u73af\u5883\u536b\u58eb\uff1a\u5b88\u62a4\u5730\u7403\u5bb6\u56ed\u7684\u5fe0\u8bda\u4f19\u4f34<\/h3>\n<p>\u9664\u4e86\u4e0a\u8ff0\u9886\u57df\uff0cDBU\u915a\u76d0\u5728\u73af\u5883\u6cbb\u7406\u65b9\u9762\u4e5f\u6709\u7740\u91cd\u8981\u7684\u5e94\u7528\u4ef7\u503c\u3002\u4f8b\u5982\uff0c\u5728\u5e9f\u6c34\u5904\u7406\u8fc7\u7a0b\u4e2d\uff0c\u5b83\u53ef\u4ee5\u4f5c\u4e3a\u50ac\u5316\u5242\u4fc3\u8fdb\u6709\u673a\u6c61\u67d3\u7269\u7684\u964d\u89e3\uff0c\u4ece\u800c\u5b9e\u73b0\u6c34\u8d44\u6e90\u7684\u5faa\u73af\u5229\u7528\u3002\u540c\u65f6\uff0c\u5176\u4f4e\u6bd2\u6027\u548c\u6613\u964d\u89e3\u7279\u6027\u4e5f\u4f7f\u5176\u6210\u4e3a\u73af\u4fdd\u578b\u50ac\u5316\u5242\u7684\u7406\u60f3\u9009\u62e9\u3002<\/p>\n<p>\u603b\u4e4b\uff0cDBU\u915a\u76d0\u51ed\u501f\u5176\u5e7f\u6cdb\u7684\u9002\u7528\u6027\u548c\u5353\u8d8a\u7684\u6027\u80fd\uff0c\u6b63\u5728\u9010\u6b65\u6e17\u900f\u5230\u5404\u4e2a\u884c\u4e1a\u4e4b\u4e2d\uff0c\u4e3a\u4eba\u7c7b\u793e\u4f1a\u7684\u53ef\u6301\u7eed\u53d1\u5c55\u6ce8\u5165\u6e90\u6e90\u4e0d\u65ad\u7684\u52a8\u529b\u3002<\/p>\n<hr \/>\n<h2>\u7eff\u8272\u50ac\u5316\u5242\u7684\u672a\u6765\uff1aDBU\u915a\u76d0\u7684\u53d1\u5c55\u524d\u666f\u4e0e\u6311\u6218<\/h2>\n<p>\u5c3d\u7ba1DBU\u915a\u76d0\u5df2\u7ecf\u5728\u591a\u4e2a\u9886\u57df\u53d6\u5f97\u4e86\u4ee4\u4eba\u77a9\u76ee\u7684\u6210\u5c31\uff0c\u4f46\u5176\u672a\u6765\u53d1\u5c55\u4ecd\u7136\u9762\u4e34\u7740\u8bf8\u591a\u673a\u9047\u4e0e\u6311\u6218\u3002\u4ece\u6280\u672f\u521b\u65b0\u5230\u5e02\u573a\u63a8\u5e7f\uff0c\u4ece\u6210\u672c\u63a7\u5236\u5230\u653f\u7b56\u652f\u6301\uff0c\u6bcf\u4e00\u4e2a\u73af\u8282\u90fd\u9700\u8981\u6211\u4eec\u6295\u5165\u66f4\u591a\u7684\u667a\u6167\u548c\u52aa\u529b\u3002<\/p>\n<h3>\u6280\u672f\u521b\u65b0\uff1a\u5411\u66f4\u9ad8\u6027\u80fd\u8fc8\u8fdb<\/h3>\n<p>\u968f\u7740\u79d1\u5b66\u6280\u672f\u7684\u4e0d\u65ad\u8fdb\u6b65\uff0cDBU\u915a\u76d0\u7684\u7814\u53d1\u4e5f\u5728\u5411\u7740\u66f4\u9ad8\u5c42\u6b21\u8fc8\u8fdb\u3002\u4e00\u65b9\u9762\uff0c\u79d1\u5b66\u5bb6\u4eec\u6b63\u5728\u5c1d\u8bd5\u901a\u8fc7\u5206\u5b50\u5de5\u7a0b\u624b\u6bb5\u4f18\u5316\u5176\u7ed3\u6784\uff0c\u4ee5\u8fdb\u4e00\u6b65\u63d0\u9ad8\u5176\u50ac\u5316\u6548\u7387\u548c\u9009\u62e9\u6027\u3002\u4f8b\u5982\uff0c\u901a\u8fc7\u5f15\u5165\u529f\u80fd\u6027\u57fa\u56e2\u6216\u6539\u53d8\u914d\u4f4d\u73af\u5883\uff0c\u53ef\u4ee5\u663e\u8457\u589e\u5f3a\u5176\u5728\u7279\u5b9a\u53cd\u5e94\u4e2d\u7684\u8868\u73b0\u3002\u53e6\u4e00\u65b9\u9762\uff0c\u7eb3\u7c73\u6280\u672f\u7684\u5e94\u7528\u4e5f\u4e3aDBU\u915a\u76d0\u5e26\u6765\u4e86\u65b0\u7684\u53ef\u80fd\u6027\u3002\u901a\u8fc7\u5c06\u5176\u8d1f\u8f7d\u5230\u7eb3\u7c73\u6750\u6599\u8868\u9762\uff0c\u4e0d\u4ec5\u53ef\u4ee5\u63d0\u9ad8\u5176\u5206\u6563\u6027\u548c\u7a33\u5b9a\u6027\uff0c\u8fd8\u80fd\u5b9e\u73b0\u5bf9\u5176\u50ac\u5316\u884c\u4e3a\u7684\u7cbe\u51c6\u8c03\u63a7\uff08\u6587\u732e\u6765\u6e90\uff1aNature Catalysis, 2022, Vol. 5, p. 890-898\uff09\u3002<\/p>\n<h3>\u6210\u672c\u63a7\u5236\uff1a\u6253\u7834\u89c4\u6a21\u5316\u5e94\u7528\u7684\u74f6\u9888<\/h3>\n<p>\u867d\u7136DBU\u915a\u76d0\u5177\u6709\u8bf8\u591a\u4f18\u70b9\uff0c\u4f46\u5176\u8f83\u9ad8\u7684\u751f\u4ea7\u6210\u672c\u4ecd\u7136\u662f\u5236\u7ea6\u5176\u5927\u89c4\u6a21\u5e94\u7528\u7684\u4e3b\u8981\u56e0\u7d20\u4e4b\u4e00\u3002\u4e3a\u6b64\uff0c\u7814\u7a76\u4eba\u5458\u6b63\u5728\u79ef\u6781\u63a2\u7d22\u66f4\u4e3a\u7ecf\u6d4e\u9ad8\u6548\u7684\u5408\u6210\u8def\u7ebf\u3002\u4f8b\u5982\uff0c\u91c7\u7528\u8fde\u7eed\u6d41\u5de5\u827a\u4ee3\u66ff\u4f20\u7edf\u7684\u6279\u6b21\u53cd\u5e94\u65b9\u5f0f\uff0c\u53ef\u4ee5\u5728\u4fdd\u8bc1\u4ea7\u54c1\u8d28\u91cf\u7684\u540c\u65f6\u5927\u5e45\u964d\u4f4e\u751f\u4ea7\u6210\u672c\u3002\u6b64\u5916\uff0c\u901a\u8fc7\u5bf9\u5e9f\u50ac\u5316\u5242\u7684\u56de\u6536\u518d\u5229\u7528\uff0c\u4e5f\u53ef\u4ee5\u6709\u6548\u51cf\u5c11\u8d44\u6e90\u6d6a\u8d39\uff0c\u63d0\u9ad8\u6574\u4f53\u7ecf\u6d4e\u6548\u76ca\u3002<\/p>\n<table>\n<thead>\n<tr>\n<th>\u6311\u6218\u7c7b\u522b<\/th>\n<th>\u4e3b\u8981\u95ee\u9898<\/th>\n<th>\u89e3\u51b3\u65b9\u6848\u793a\u4f8b<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u751f\u4ea7\u6210\u672c<\/td>\n<td>\u5408\u6210\u8def\u7ebf\u590d\u6742\u3001\u539f\u6599\u6602\u8d35<\/td>\n<td>\u5f00\u53d1\u8fde\u7eed\u6d41\u5de5\u827a\u3001\u4f18\u5316\u539f\u6599\u9009\u62e9<\/td>\n<\/tr>\n<tr>\n<td>\u89c4\u6a21\u5316\u5e94\u7528<\/td>\n<td>\u5de5\u827a\u653e\u5927\u96be\u5ea6\u8f83\u5927<\/td>\n<td>\u5f15\u5165\u667a\u80fd\u63a7\u5236\u7cfb\u7edf\u3001\u52a0\u5f3a\u5de5\u7a0b\u8bbe\u8ba1<\/td>\n<\/tr>\n<tr>\n<td>\u73af\u5883\u5f71\u54cd<\/td>\n<td>\u5e9f\u5f03\u7269\u5904\u7406\u4e0d\u591f\u5b8c\u5584<\/td>\n<td>\u63d0\u9ad8\u56de\u6536\u5229\u7528\u7387\u3001\u63a2\u7d22\u7eff\u8272\u5de5\u827a<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<h3>\u653f\u7b56\u652f\u6301\uff1a\u4e3a\u7eff\u8272\u53d1\u5c55\u4fdd\u9a7e\u62a4\u822a<\/h3>\n<p>\u548c\u76f8\u5173\u673a\u6784\u7684\u652f\u6301\u5bf9\u4e8eDBU\u915a\u76d0\u7684\u63a8\u5e7f\u5e94\u7528\u81f3\u5173\u91cd\u8981\u3002\u8fd1\u5e74\u6765\uff0c\u5404\u56fd\u7eb7\u7eb7\u51fa\u53f0\u4e86\u4e00\u7cfb\u5217\u9f13\u52b1\u7eff\u8272\u5316\u5b66\u53d1\u5c55\u7684\u653f\u7b56\u63aa\u65bd\uff0c\u4e3a\u5305\u62ecDBU\u915a\u76d0\u5728\u5185\u7684\u65b0\u578b\u50ac\u5316\u5242\u521b\u9020\u4e86\u826f\u597d\u7684\u5916\u90e8\u73af\u5883\u3002\u4f8b\u5982\uff0c\u6b27\u76df\u7684\u201c\u5730\u5e73\u7ebf2020\u201d\u8ba1\u5212\u5c31\u660e\u786e\u5c06\u7eff\u8272\u50ac\u5316\u5242\u7814\u53d1\u5217\u4e3a\u4f18\u5148\u8d44\u52a9\u9886\u57df\uff0c\u800c\u4e2d\u56fd\u7684\u300a\u201c\u5341\u56db\u4e94\u201d\u89c4\u5212\u300b\u4e5f\u5c06\u7eff\u8272\u5316\u5de5\u6280\u672f\u5217\u4e3a\u91cd\u70b9\u53d1\u5c55\u65b9\u5411\u4e4b\u4e00\u3002<\/p>\n<p>\u7136\u800c\uff0c\u653f\u7b56\u652f\u6301\u4e0d\u4ec5\u4ec5\u662f\u8d44\u91d1\u4e0a\u7684\u6295\u5165\uff0c\u8fd8\u9700\u8981\u5728\u6807\u51c6\u5236\u5b9a\u3001\u5e02\u573a\u76d1\u7ba1\u7b49\u65b9\u9762\u7ed9\u4e88\u66f4\u591a\u5173\u6ce8\u3002\u53ea\u6709\u5efa\u7acb\u8d77\u5b8c\u5584\u7684\u6cd5\u5f8b\u6cd5\u89c4\u4f53\u7cfb\uff0c\u624d\u80fd\u786e\u4fddDBU\u915a\u76d0\u7b49\u7eff\u8272\u5316\u5b66\u54c1\u7684\u5b89\u5168\u4f7f\u7528\uff0c\u771f\u6b63\u5b9e\u73b0\u7ecf\u6d4e\u6548\u76ca\u4e0e\u793e\u4f1a\u6548\u76ca\u7684\u7edf\u4e00\u3002<\/p>\n<h3>\u5e02\u573a\u5c55\u671b\uff1a\u5e7f\u9614\u5929\u5730\u5927\u6709\u53ef\u4e3a<\/h3>\n<p>\u6839\u636e\u6743\u5a01\u673a\u6784\u9884\u6d4b\uff0c\u5168\u7403\u7eff\u8272\u50ac\u5316\u5242\u5e02\u573a\u89c4\u6a21\u5728\u672a\u6765\u5341\u5e74\u5185\u5c06\u4ee5\u5e74\u57478%\u4ee5\u4e0a\u7684\u901f\u5ea6\u589e\u957f\uff0c\u800cDBU\u915a\u76d0\u4f5c\u4e3a\u5176\u4e2d\u7684\u4f7c\u4f7c\u8005\uff0c\u65e0\u7591\u5c06\u8fce\u6765\u66f4\u5927\u7684\u53d1\u5c55\u673a\u9047\u3002\u5c24\u5176\u662f\u5728\u65b0\u80fd\u6e90\u3001\u751f\u7269\u533b\u836f\u7b49\u6218\u7565\u6027\u65b0\u5174\u4ea7\u4e1a\u5feb\u901f\u5d1b\u8d77\u7684\u80cc\u666f\u4e0b\uff0c\u5176\u5e02\u573a\u9700\u6c42\u6709\u671b\u5448\u73b0\u7206\u53d1\u5f0f\u589e\u957f\u3002<\/p>\n<p>\u5f53\u7136\uff0c\u5e02\u573a\u7ade\u4e89\u4e5f\u5c06\u53d8\u5f97\u66f4\u52a0\u6fc0\u70c8\u3002\u9762\u5bf9\u6765\u81ea\u5176\u4ed6\u7c7b\u578b\u50ac\u5316\u5242\u7684\u6311\u6218\uff0cDBU\u915a\u76d0\u9700\u8981\u4e0d\u65ad\u63d0\u5347\u81ea\u8eab\u7684\u6838\u5fc3\u7ade\u4e89\u529b\uff0c\u901a\u8fc7\u6280\u672f\u521b\u65b0\u548c\u54c1\u724c\u5efa\u8bbe\u8d62\u5f97\u66f4\u591a\u5ba2\u6237\u7684\u4fe1\u8d56\u3002\u540c\u65f6\uff0c\u4f01\u4e1a\u8fd8\u9700\u8981\u6ce8\u91cd\u4e0e\u4e0b\u6e38\u7528\u6237\u7684\u6df1\u5ea6\u5408\u4f5c\uff0c\u5171\u540c\u5f00\u53d1\u66f4\u591a\u5e94\u7528\u573a\u666f\uff0c\u62d3\u5c55\u4ea7\u54c1\u4ef7\u503c\u94fe\u3002<\/p>\n<hr \/>\n<h2>\u7ed3\u8bed\uff1aDBU\u915a\u76d0\u2014\u2014\u7eff\u8272\u5316\u5b66\u7684\u7480\u74a8\u660e\u73e0<\/h2>\n<p>DBU\u915a\u76d0\uff08CAS 57671-19-9\uff09\u4f5c\u4e3a\u7eff\u8272\u50ac\u5316\u5242\u9886\u57df\u7684\u4e00\u9897\u7480\u74a8\u660e\u73e0\uff0c\u6b63\u5728\u4ee5\u81ea\u5df1\u7684\u65b9\u5f0f\u6539\u53d8\u7740\u6211\u4eec\u7684\u4e16\u754c\u3002\u5b83\u4e0d\u4ec5\u662f\u4e00\u79cd\u9ad8\u6548\u7684\u5316\u5b66\u5de5\u5177\uff0c\u66f4\u662f\u4e00\u4f4d\u8df5\u884c\u53ef\u6301\u7eed\u53d1\u5c55\u7406\u5ff5\u7684\u5fe0\u5b9e\u4fe1\u5f92\u3002\u4ece\u7cbe\u7ec6\u5316\u5de5\u5230\u751f\u7269\u533b\u836f\uff0c\u4ece\u6e05\u6d01\u80fd\u6e90\u5230\u73af\u5883\u6cbb\u7406\uff0c\u5b83\u7684\u8eab\u5f71\u65e0\u5904\u4e0d\u5728\uff0c\u4e3a\u5404\u884c\u5404\u4e1a\u6ce8\u5165\u4e86\u65b0\u7684\u6d3b\u529b\u4e0e\u5e0c\u671b\u3002<\/p>\n<p>\u7136\u800c\uff0c\u6211\u4eec\u4e5f\u5fc5\u987b\u6e05\u9192\u5730\u8ba4\u8bc6\u5230\uff0cDBU\u915a\u76d0\u7684\u53d1\u5c55\u4e4b\u8def\u5e76\u975e\u4e00\u5e06\u98ce\u987a\u3002\u53ea\u6709\u901a\u8fc7\u6301\u7eed\u7684\u6280\u672f\u521b\u65b0\u3001\u5408\u7406\u7684\u6210\u672c\u63a7\u5236\u4ee5\u53ca\u5f3a\u6709\u529b\u7684\u653f\u7b56\u652f\u6301\uff0c\u624d\u80fd\u8ba9\u8fd9\u9897\u660e\u73e0\u7efd\u653e\u51fa\u66f4\u52a0\u8000\u773c\u7684\u5149\u8292\u3002\u8ba9\u6211\u4eec\u643a\u624b\u5171\u8fdb\uff0c\u4e3a\u5b9e\u73b0\u4eba\u4e0e\u81ea\u7136\u548c\u8c10\u5171\u751f\u7684\u7f8e\u597d\u613f\u666f\u8d21\u732e\u81ea\u5df1\u7684\u529b\u91cf\uff01<\/p>\n<p>\u6269\u5c55\u9605\u8bfb:<a href=\"https:\/\/www.cyclohexylamine.net\/high-quality-dmcha-cas-98-94-2-n-dimethylcyclohexylamine\/\">https:\/\/www.cyclohexylamine.net\/high-quality-dmcha-cas-98-94-2-n-dimethylcyclohexylamine\/<\/a><\/br><br \/>\u6269\u5c55\u9605\u8bfb:<a href=\"https:\/\/www.bdmaee.net\/fentacat-f13-catalyst-cas80284-38-9-solvay\/\">https:\/\/www.bdmaee.net\/fentacat-f13-catalyst-cas80284-38-9-solvay\/<\/a><\/br><br \/>\u6269\u5c55\u9605\u8bfb:<a href=\"https:\/\/www.newtopchem.com\/archives\/39412\">https:\/\/www.newtopchem.com\/archives\/39412<\/a><\/br><br \/>\u6269\u5c55\u9605\u8bfb:<a href=\"https:\/\/www.cyclohexylamine.net\/2-methylcyclohexylamine\/\">https:\/\/www.cyclohexylamine.net\/2-methylcyclohexylamine\/<\/a><\/br><br \/>\u6269\u5c55\u9605\u8bfb:<a href=\"https:\/\/www.bdmaee.net\/butyl-tin-triisooctoate-cas23850-94-4-fascat9102-catalyst\/\">https:\/\/www.bdmaee.net\/butyl-tin-triisooctoate-cas23850-94-4-fascat9102-catalyst\/<\/a><\/br><br \/>\u6269\u5c55\u9605\u8bfb:<a href=\"https:\/\/www.bdmaee.net\/polycat-41-catalyst-cas10294-43-5-evonik-germany\/\">https:\/\/www.bdmaee.net\/polycat-41-catalyst-cas10294-43-5-evonik-germany\/<\/a><\/br><br \/>\u6269\u5c55\u9605\u8bfb:<a href=\"https:\/\/www.newtopchem.com\/archives\/1116\">https:\/\/www.newtopchem.com\/archives\/1116<\/a><\/br><br \/>\u6269\u5c55\u9605\u8bfb:<a href=\"https:\/\/www.newtopchem.com\/archives\/39962\">https:\/\/www.newtopchem.com\/archives\/39962<\/a><\/br><br \/>\u6269\u5c55\u9605\u8bfb:<a href=\"https:\/\/www.morpholine.org\/elastomer-environmental-protection-catalyst-environmental-protection-catalyst\/\">https:\/\/www.morpholine.org\/elastomer-environmental-protection-catalyst-environmental-protection-catalyst\/<\/a><\/br><br \/>\u6269\u5c55\u9605\u8bfb:<a href=\"https:\/\/www.newtopchem.com\/archives\/1025\">https:\/\/www.newtopchem.com\/archives\/1025<\/a><\/br><\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u7eff\u8272\u50ac\u5316\u5242\uff1aDBU\u915a\u76d0\uff08CAS 57671-19-9\uff09\u7684\u524d\u4e16\u4eca\u751f \u5728\u53ef\u6301\u7eed\u53d1\u5c55\u7684\u6d6a\u6f6e\u4e2d\uff0c\u7eff\u8272\u5316\u5b66\u6b63\u4ee5\u524d\u6240\u672a\u6709\u7684\u901f\u5ea6\u6539\u53d8\u7740\u6211\u4eec\u7684\u4e16\u754c\u3002\u800c\u5728\u8fd9\u573a\u53d8\u9769\u4e2d\uff0cDBU\u915a\u76d0\uff08CAS 57671-19-9\uff09\u72b9\u5982\u4e00\u9897\u8000\u773c\u7684\u65b0\u661f\uff0c\u5728\u4f17\u591a\u50ac\u5316\u5242\u4e2d\u8131\u9896\u800c\u51fa\uff0c\u6210\u4e3a\u63a8\u52a8\u7eff\u8272\u5316\u5b66\u53d1\u5c55\u7684\u91cd\u8981\u529b\u91cf\u3002\u5b83\u4e0d\u4ec5\u662f\u4e00\u79cd\u9ad8\u6548\u7684\u6709\u673a\u50ac\u5316\u5242\uff0c\u66f4\u662f\u4e00\u4f4d\u9ed8\u9ed8\u65e0\u95fb\u7684\u73af\u4fdd\u5148 &#8230;<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"standard","meta":[],"categories":[3],"tags":[4691],"_links":{"self":[{"href":"https:\/\/www.k-15.cn\/wp-json\/wp\/v2\/posts\/5231"}],"collection":[{"href":"https:\/\/www.k-15.cn\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.k-15.cn\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.k-15.cn\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.k-15.cn\/wp-json\/wp\/v2\/comments?post=5231"}],"version-history":[{"count":0,"href":"https:\/\/www.k-15.cn\/wp-json\/wp\/v2\/posts\/5231\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.k-15.cn\/wp-json\/wp\/v2\/media?parent=5231"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.k-15.cn\/wp-json\/wp\/v2\/categories?post=5231"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.k-15.cn\/wp-json\/wp\/v2\/tags?post=5231"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}