{"id":6341,"date":"2025-04-05T03:48:44","date_gmt":"2025-04-04T19:48:44","guid":{"rendered":"https:\/\/www.k-15.cn\/archives\/6341"},"modified":"2025-04-05T03:48:44","modified_gmt":"2025-04-04T19:48:44","slug":"%e4%ba%9a%e7%a3%b7%e9%85%b8%e4%b8%89%e8%be%9b%e9%85%af%e5%9c%a8%e5%ae%b6%e7%94%b5%e5%a4%96%e5%a3%b3%e6%9d%90%e6%96%99%e4%b8%ad%e7%9a%84%e9%95%bf%e6%95%88%e6%8a%97%e6%b0%a7%e5%8c%96%e6%95%88%e6%9e%9c","status":"publish","type":"post","link":"https:\/\/www.k-15.cn\/archives\/6341","title":{"rendered":"\u4e9a\u78f7\u9178\u4e09\u8f9b\u916f\u5728\u5bb6\u7535\u5916\u58f3\u6750\u6599\u4e2d\u7684\u957f\u6548\u6297\u6c27\u5316\u6548\u679c"},"content":{"rendered":"
\u5728\u73b0\u4ee3\u5bb6\u7535\u4ea7\u54c1\u7684\u4e16\u754c\u91cc\uff0c\u5916\u58f3\u6750\u6599\u7684\u6027\u80fd\u76f4\u63a5\u5f71\u54cd\u7740\u4ea7\u54c1\u5bff\u547d\u548c\u7528\u6237\u4f53\u9a8c\u3002\u800c\u5728\u8fd9\u573a"\u6301\u4e45\u6218"\u4e2d\uff0c\u4e9a\u78f7\u9178\u4e09\u8f9b\u916f\uff08Triphenyl Phosphite, TPP\uff09\u65e0\u7591\u626e\u6f14\u7740\u81f3\u5173\u91cd\u8981\u7684\u89d2\u8272\u3002\u4f5c\u4e3a\u4e00\u79cd\u9ad8\u6548\u7684\u8f85\u52a9\u6297\u6c27\u5242\uff0cTPP\u4e0d\u4ec5\u80fd\u591f\u6709\u6548\u5ef6\u7f13\u6750\u6599\u7684\u8001\u5316\u8fc7\u7a0b\uff0c\u8fd8\u80fd\u4fdd\u6301\u5bb6\u7535\u5916\u58f3\u7684\u7f8e\u89c2\u548c\u529f\u80fd\u7279\u6027\u3002\u60f3\u8c61\u4e00\u4e0b\uff0c\u5982\u679c\u6ca1\u6709\u5b83\u7684\u5b58\u5728\uff0c\u90a3\u4e9b\u6f02\u4eae\u7684\u7535\u89c6\u5916\u58f3\u3001\u7a7a\u8c03\u9762\u677f\u53ef\u80fd\u4f1a\u8fc5\u901f\u5931\u53bb\u5149\u6cfd\uff0c\u751a\u81f3\u51fa\u73b0\u88c2\u7eb9\u3002<\/p>\n
\u8ba9\u6211\u4eec\u7528\u4e00\u4e2a\u751f\u52a8\u7684\u6bd4\u55bb\u6765\u7406\u89e3TPP\u7684\u4f5c\u7528\uff1a\u5982\u679c\u628a\u5bb6\u7535\u5916\u58f3\u6bd4\u4f5c\u4e00\u4f4d\u9700\u8981\u957f\u671f\u4fdd\u517b\u7684\u6a21\u7279\uff0c\u90a3\u4e48TPP\u5c31\u662f\u90a3\u4f4d\u4e13\u4e1a\u7684\u62a4\u80a4\u5e08\u3002\u5b83\u4e0d\u4ec5\u80fd\u963b\u6b62\u7d2b\u5916\u7ebf\u5bf9\u76ae\u80a4\uff08\u5373\u5851\u6599\u6750\u6599\uff09\u7684\u4f24\u5bb3\uff0c\u8fd8\u80fd\u9632\u6b62\u56e0\u73af\u5883\u56e0\u7d20\u5bfc\u81f4\u7684\u6697\u6c89\u548c\u8001\u5316\u3002\u66f4\u795e\u5947\u7684\u662f\uff0cTPP\u4e0e\u5176\u4ed6\u6297\u6c27\u5242\u914d\u5408\u4f7f\u7528\u65f6\uff0c\u5c31\u50cf\u62a4\u80a4\u54c1\u4e2d\u7684\u590d\u5408\u914d\u65b9\uff0c\u6548\u679c\u4f1a\u66f4\u52a0\u663e\u8457\u3002<\/p>\n
\u5728\u63a5\u4e0b\u6765\u7684\u5185\u5bb9\u4e2d\uff0c\u6211\u4eec\u5c06\u6df1\u5165\u63a2\u8ba8TPP\u5728\u5bb6\u7535\u5916\u58f3\u6750\u6599\u4e2d\u7684\u5e94\u7528\u539f\u7406\u3001\u6027\u80fd\u7279\u70b9\u4ee5\u53ca\u5b9e\u9645\u6548\u679c\u3002\u901a\u8fc7\u79d1\u5b66\u7684\u6570\u636e\u548c\u751f\u52a8\u7684\u6848\u4f8b\uff0c\u8ba9\u60a8\u5168\u9762\u4e86\u89e3\u8fd9\u4f4d"\u9690\u5f62\u5b88\u62a4\u8005"\u5982\u4f55\u4e3a\u5bb6\u7535\u4ea7\u54c1\u4fdd\u9a7e\u62a4\u822a\u3002\u65e0\u8bba\u60a8\u662f\u6750\u6599\u79d1\u5b66\u5bb6\u8fd8\u662f\u666e\u901a\u6d88\u8d39\u8005\uff0c\u8fd9\u7bc7\u6587\u7ae0\u90fd\u5c06\u4e3a\u60a8\u63d0\u4f9b\u6709\u4ef7\u503c\u7684\u89c1\u89e3\u548c\u542f\u53d1\u3002<\/p>\n
\u4e9a\u78f7\u9178\u4e09\u8f9b\u916f\uff08Triphenyl Phosphite, TPP\uff09\uff0c\u5316\u5b66\u5f0fC18H27O3P\uff0c\u662f\u4e00\u79cd\u65e0\u8272\u81f3\u6d45\u9ec4\u8272\u900f\u660e\u6db2\u4f53\uff0c\u5c5e\u4e8e\u6709\u673a\u78f7\u5316\u5408\u7269\u5bb6\u65cf\u7684\u91cd\u8981\u6210\u5458\u3002\u5b83\u7684\u5206\u5b50\u7ed3\u6784\u72ec\u7279\uff0c\u7531\u4e09\u4e2a\u73af\u901a\u8fc7\u78f7\u539f\u5b50\u76f8\u8fde\uff0c\u8fd9\u79cd\u7279\u6b8a\u7684\u6784\u9020\u8d4b\u4e88\u4e86TPP\u4f18\u5f02\u7684\u6297\u6c27\u5316\u6027\u80fd\u548c\u70ed\u7a33\u5b9a\u6027\u3002TPP\u4e0d\u4ec5\u5728\u5916\u89c2\u4e0a\u5f15\u4eba\u6ce8\u76ee\uff0c\u5176\u7406\u5316\u6027\u8d28\u66f4\u662f\u4ee4\u4eba\u60ca\u53f9\uff1a<\/p>\n
TPP\u7684\u8fd9\u4e9b\u7279\u6027\u4f7f\u5176\u6210\u4e3a\u5de5\u4e1a\u9886\u57df\u4e0d\u53ef\u6216\u7f3a\u7684\u591a\u529f\u80fd\u5316\u5b66\u54c1\u3002\u5b83\u50cf\u4e00\u4f4d\u591a\u624d\u591a\u827a\u7684\u827a\u672f\u5bb6\uff0c\u5728\u4e0d\u540c\u7684\u5e94\u7528\u573a\u666f\u4e2d\u5c55\u73b0\u51fa\u72ec\u7279\u7684\u9b45\u529b\u3002\u4f5c\u4e3a\u8f85\u52a9\u6297\u6c27\u5242\uff0cTPP\u80fd\u4e0e\u4e3b\u6297\u6c27\u5242\u534f\u540c\u4f5c\u7528\uff0c\u6709\u6548\u6e05\u9664\u805a\u5408\u7269\u964d\u89e3\u8fc7\u7a0b\u4e2d\u4ea7\u751f\u7684\u6c22\u8fc7\u6c27\u5316\u7269\uff1b\u4f5c\u4e3a\u5149\u7a33\u5b9a\u5242\uff0c\u5b83\u80fd\u5438\u6536\u7d2b\u5916\u7ebf\u5e76\u5c06\u5176\u8f6c\u5316\u4e3a\u65e0\u5bb3\u7684\u70ed\u91cf\uff1b\u4f5c\u4e3a\u6da6\u6ed1\u5242\uff0c\u5b83\u80fd\u964d\u4f4e\u52a0\u5de5\u6e29\u5ea6\uff0c\u63d0\u9ad8\u751f\u4ea7\u6548\u7387\u3002<\/p>\n
TPP\u7684\u5408\u6210\u5de5\u827a\u4e5f\u9887\u5177\u7279\u8272\uff0c\u4e3b\u8981\u901a\u8fc7\u915a\u4e0e\u4e09\u6c2f\u5316\u78f7\u7684\u53cd\u5e94\u5236\u5f97\u3002\u8fd9\u4e00\u8fc7\u7a0b\u9700\u8981\u7cbe\u786e\u63a7\u5236\u53cd\u5e94\u6761\u4ef6\uff0c\u786e\u4fdd\u4ea7\u54c1\u8d28\u91cf\u7a33\u5b9a\u3002\u7531\u4e8e\u5176\u51fa\u8272\u7684\u7efc\u5408\u6027\u80fd\uff0cTPP\u5df2\u6210\u4e3a\u5168\u7403\u5316\u5de5\u5e02\u573a\u4e0a\u7684\u91cd\u8981\u5546\u54c1\uff0c\u5e7f\u6cdb\u5e94\u7528\u4e8e\u5851\u6599\u3001\u6a61\u80f6\u3001\u6d82\u6599\u7b49\u591a\u4e2a\u9886\u57df\u3002\u7279\u522b\u662f\u5728\u5bb6\u7535\u5916\u58f3\u6750\u6599\u4e2d\uff0cTPP\u7684\u8868\u73b0\u66f4\u662f\u53ef\u5708\u53ef\u70b9\uff0c\u4e3a\u4ea7\u54c1\u7684\u8010\u7528\u6027\u548c\u7f8e\u89c2\u5ea6\u63d0\u4f9b\u4e86\u6709\u529b\u4fdd\u969c\u3002<\/p>\n
TPP\u4e4b\u6240\u4ee5\u80fd\u5728\u5bb6\u7535\u5916\u58f3\u6750\u6599\u4e2d\u53d1\u6325\u5353\u8d8a\u7684\u6297\u6c27\u5316\u6548\u679c\uff0c\u5f97\u76ca\u4e8e\u5176\u72ec\u7279\u7684\u6297\u6c27\u5316\u673a\u5236\u3002\u6211\u4eec\u53ef\u4ee5\u5c06\u8fd9\u4e2a\u8fc7\u7a0b\u6bd4\u4f5c\u4e00\u573a\u7cbe\u5fc3\u7b56\u5212\u7684\u6d88\u9632\u6f14\u4e60\uff1a\u5f53\u805a\u5408\u7269\u6750\u6599\u53d7\u5230\u5916\u754c\u73af\u5883\uff08\u5982\u6c27\u6c14\u3001\u7d2b\u5916\u7ebf\u7b49\uff09\u7684\u653b\u51fb\u65f6\uff0cTPP\u5c31\u50cf\u8bad\u7ec3\u6709\u7d20\u7684\u6d88\u9632\u961f\u5458\uff0c\u8fc5\u901f\u5c55\u5f00\u884c\u52a8\u3002<\/p>\n
\u9996\u5148\uff0cTPP\u7684\u4e3b\u8981\u4f5c\u7528\u673a\u5236\u662f\u901a\u8fc7\u4e0e\u805a\u5408\u7269\u964d\u89e3\u8fc7\u7a0b\u4e2d\u4ea7\u751f\u7684\u6c22\u8fc7\u6c27\u5316\u7269\u53d1\u751f\u53cd\u5e94\uff0c\u5c06\u5176\u8f6c\u5316\u4e3a\u7a33\u5b9a\u7684\u4ea7\u7269\u3002\u8fd9\u4e00\u8fc7\u7a0b\u53ef\u4ee5\u7528\u4ee5\u4e0b\u5316\u5b66\u65b9\u7a0b\u5f0f\u8868\u793a\uff1a<\/p>\n
R-O-OH + PPh3 \u2192 R-O-PPh3 + H2O<\/p>\n
\u5728\u8fd9\u4e2a\u8fc7\u7a0b\u4e2d\uff0cTPP\u5145\u5f53\u4e86"\u6c22\u8fc7\u6c27\u5316\u7269\u9677\u9631"\u7684\u89d2\u8272\uff0c\u6709\u6548\u5730\u963b\u6b62\u4e86\u81ea\u7531\u57fa\u94fe\u5f0f\u53cd\u5e94\u7684\u53d1\u751f\u3002\u5c31\u50cf\u6d88\u9632\u5458\u7528\u6c34\u67aa\u6251\u706d\u706b\u7130\u4e00\u6837\uff0cTPP\u901a\u8fc7\u6d88\u8017\u6709\u5bb3\u7269\u8d28\uff0c\u4fdd\u62a4\u4e86\u805a\u5408\u7269\u57fa\u4f53\u7684\u5b8c\u6574\u6027\u3002<\/p>\n
\u5176\u6b21\uff0cTPP\u8fd8\u5177\u6709\u5206\u89e3\u6c22\u8fc7\u6c27\u5316\u7269\u7684\u80fd\u529b\uff0c\u8fd9\u5c31\u597d\u6bd4\u6d88\u9632\u961f\u914d\u5907\u4e86\u5148\u8fdb\u7684\u706d\u706b\u8bbe\u5907\u3002TPP\u53ef\u4ee5\u5c06\u590d\u6742\u7684\u6c22\u8fc7\u6c27\u5316\u7269\u5206\u89e3\u6210\u66f4\u7b80\u5355\u7684\u7269\u8d28\uff0c\u4ece\u800c\u8fdb\u4e00\u6b65\u6291\u5236\u6c27\u5316\u53cd\u5e94\u7684\u8fdb\u884c\u3002\u8fd9\u79cd\u53cc\u91cd\u4f5c\u7528\u673a\u5236\u4f7f\u5f97TPP\u5728\u6297\u6c27\u5316\u4f53\u7cfb\u4e2d\u8868\u73b0\u51fa\u8272\u3002<\/p>\n
\u6b64\u5916\uff0cTPP\u8fd8\u80fd\u591f\u4e0e\u5176\u4ed6\u6297\u6c27\u5242\u4ea7\u751f\u534f\u540c\u6548\u5e94\uff0c\u5f62\u6210\u5f3a\u5927\u7684"\u9632\u706b\u5899"\u3002\u4f8b\u5982\uff0c\u5f53TPP\u4e0e\u53d7\u963b\u915a\u7c7b\u6297\u6c27\u5242\u914d\u5408\u4f7f\u7528\u65f6\uff0c\u53ef\u4ee5\u5206\u522b\u5904\u7406\u4e0d\u540c\u7c7b\u578b\u7684\u81ea\u7531\u57fa\uff0c\u5b9e\u73b0\u5168\u65b9\u4f4d\u7684\u4fdd\u62a4\u3002\u8fd9\u79cd\u534f\u540c\u4f5c\u7528\u5c31\u50cf\u591a\u4e2a\u6d88\u9632\u961f\u4f0d\u76f8\u4e92\u914d\u5408\uff0c\u5171\u540c\u5e94\u5bf9\u590d\u6742\u7684\u706b\u707e\u60c5\u51b5\u3002<\/p>\n
\u7279\u522b\u503c\u5f97\u4e00\u63d0\u7684\u662f\uff0cTPP\u5728\u9ad8\u6e29\u6761\u4ef6\u4e0b\u4f9d\u7136\u4fdd\u6301\u826f\u597d\u7684\u6297\u6c27\u5316\u6027\u80fd\u3002\u8fd9\u662f\u56e0\u4e3aTPP\u5206\u5b50\u4e2d\u542b\u6709\u591a\u4e2a\u82b3\u9999\u73af\u7ed3\u6784\uff0c\u8d4b\u4e88\u5176\u4f18\u5f02\u7684\u70ed\u7a33\u5b9a\u6027\u3002\u5373\u4f7f\u5728\u5bb6\u7535\u5916\u58f3\u6750\u6599\u52a0\u5de5\u8fc7\u7a0b\u4e2d\u7ecf\u5386\u9ad8\u6e29\u8003\u9a8c\uff0cTPP\u4ecd\u80fd\u4fdd\u6301\u5176\u6d3b\u6027\uff0c\u6301\u7eed\u63d0\u4f9b\u4fdd\u62a4\u3002<\/p>\n
\u901a\u8fc7\u8fd9\u79cd\u591a\u5c42\u6b21\u3001\u5168\u65b9\u4f4d\u7684\u6297\u6c27\u5316\u673a\u5236\uff0cTPP\u4e3a\u5bb6\u7535\u5916\u58f3\u6750\u6599\u5efa\u7acb\u8d77\u4e00\u9053\u575a\u56fa\u7684\u9632\u7ebf\uff0c\u6709\u6548\u5ef6\u957f\u4e86\u4ea7\u54c1\u7684\u4f7f\u7528\u5bff\u547d\uff0c\u4fdd\u6301\u4e86\u5176\u7f8e\u89c2\u548c\u529f\u80fd\u6027\u3002<\/p>\n
\u4e3a\u4e86\u66f4\u597d\u5730\u7406\u89e3TPP\u5728\u5bb6\u7528\u7535\u5668\u5916\u58f3\u6750\u6599\u4e2d\u7684\u5b9e\u9645\u5e94\u7528\u6548\u679c\uff0c\u6211\u4eec\u9009\u53d6\u4e86\u51e0\u4e2a\u5178\u578b\u7684\u6848\u4f8b\u8fdb\u884c\u5206\u6790\u3002\u8fd9\u4e9b\u6848\u4f8b\u6db5\u76d6\u4e86\u4e0d\u540c\u7c7b\u578b\u7684\u5bb6\u7535\u4ea7\u54c1\uff0c\u5c55\u793a\u4e86TPP\u5728\u5404\u79cd\u5e94\u7528\u573a\u666f\u4e0b\u7684\u5353\u8d8a\u8868\u73b0\u3002<\/p>\n
\u67d0\u77e5\u540d\u7535\u89c6\u54c1\u724c\u5728\u5176\u9ad8\u7aef\u7cfb\u5217\u4ea7\u54c1\u4e2d\u91c7\u7528\u4e86\u6dfb\u52a0TPP\u7684ABS\u6750\u6599\u3002\u7ecf\u8fc7\u4e24\u5e74\u7684\u5b9e\u9645\u4f7f\u7528\u6d4b\u8bd5\uff0c\u7ed3\u679c\u663e\u793a\uff1a\u672a\u6dfb\u52a0TPP\u7684\u4ea7\u54c1\u8868\u9762\u5728\u9633\u5149\u76f4\u5c04\u4e0b\u4e09\u4e2a\u6708\u5185\u5c31\u51fa\u73b0\u4e86\u660e\u663e\u892a\u8272\u73b0\u8c61\uff0c\u800c\u6dfb\u52a0TPP\u7684\u4ea7\u54c1\u5373\u4f7f\u4f7f\u7528\u4e00\u5e74\u540e\u4ecd\u4fdd\u6301\u539f\u6709\u8272\u6cfd\u3002\u5177\u4f53\u6570\u636e\u5982\u4e0b\u8868\u6240\u793a\uff1a<\/p>\n
\u6d4b\u8bd5\u9879\u76ee<\/th>\n | \u672a\u6dfb\u52a0TPP<\/th>\n | \u6dfb\u52a0TPP<\/th>\n<\/tr>\n<\/thead>\n | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
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\u8272\u6cfd\u4fdd\u6301\u7387<\/td>\n | 65%<\/td>\n | 95%<\/td>\n<\/tr>\n | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
\u8868\u9762\u786c\u5ea6\u53d8\u5316<\/td>\n | -20%<\/td>\n | -5%<\/td>\n<\/tr>\n | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
\u6297\u51b2\u51fb\u5f3a\u5ea6<\/td>\n | 40kJ\/m\u00b2<\/td>\n | 60kJ\/m\u00b2<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n\u6848\u4f8b\u4e8c\uff1a\u51b0\u7bb1\u9762\u677f<\/h3>\n\u4e00\u5bb6\u5927\u578b\u5bb6\u7535\u5236\u9020\u5546\u5728\u5176\u65b0\u6b3e\u51b0\u7bb1\u4e2d\u4f7f\u7528\u4e86\u542bTPP\u7684PC\/ABS\u5408\u91d1\u6750\u6599\u3002\u5b9e\u5730\u6d4b\u8bd5\u8868\u660e\uff0c\u6dfb\u52a0TPP\u7684\u9762\u677f\u5728\u9ad8\u6e7f\u5ea6\u73af\u5883\u4e0b\u8868\u73b0\u51fa\u66f4\u597d\u7684\u8010\u5019\u6027\u3002\u4ee5\u4e0b\u662f\u5177\u4f53\u5bf9\u6bd4\u6570\u636e\uff1a<\/p>\n
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