{"id":6551,"date":"2025-04-06T22:05:57","date_gmt":"2025-04-06T14:05:57","guid":{"rendered":"https:\/\/www.k-15.cn\/archives\/6551"},"modified":"2025-04-06T22:05:57","modified_gmt":"2025-04-06T14:05:57","slug":"%e6%8a%97%e6%b0%a7%e5%89%82dhop%e5%9c%a8%e7%94%b5%e5%ad%90%e7%94%b5%e5%99%a8%e8%a1%8c%e4%b8%9a%e4%b8%ad%e7%9a%84%e6%8a%97%e6%b0%a7%e5%8c%96%e4%bd%9c%e7%94%a8","status":"publish","type":"post","link":"https:\/\/www.k-15.cn\/archives\/6551","title":{"rendered":"\u6297\u6c27\u5242DHOP\u5728\u7535\u5b50\u7535\u5668\u884c\u4e1a\u4e2d\u7684\u6297\u6c27\u5316\u4f5c\u7528"},"content":{"rendered":"

\u6297\u6c27\u5242DHOP\uff1a\u7535\u5b50\u7535\u5668\u884c\u4e1a\u4e2d\u7684\u201c\u6297\u6c27\u5316\u536b\u58eb\u201d<\/h1>\n

\u5728\u5f53\u4eca\u8fd9\u4e2a\u9ad8\u79d1\u6280\u98de\u901f\u53d1\u5c55\u7684\u65f6\u4ee3\uff0c\u7535\u5b50\u7535\u5668\u4ea7\u54c1\u5df2\u7ecf\u6210\u4e3a\u6211\u4eec\u751f\u6d3b\u4e2d\u4e0d\u53ef\u6216\u7f3a\u7684\u4e00\u90e8\u5206\u3002\u4ece\u667a\u80fd\u624b\u673a\u5230\u5bb6\u7528\u7535\u5668\uff0c\u518d\u5230\u5de5\u4e1a\u8bbe\u5907\uff0c\u6bcf\u4e00\u4e2a\u5c0f\u5c0f\u7684\u90e8\u4ef6\u90fd\u53ef\u80fd\u51b3\u5b9a\u7740\u6574\u4e2a\u7cfb\u7edf\u7684\u7a33\u5b9a\u6027\u548c\u5bff\u547d\u3002\u800c\u5728\u8fd9\u5176\u4e2d\uff0c\u6709\u4e00\u79cd\u770b\u4f3c\u4e0d\u8d77\u773c\u5374\u81f3\u5173\u91cd\u8981\u7684\u5316\u5b66\u7269\u8d28\u2014\u2014\u6297\u6c27\u5242DHOP\uff08Di(2-hydroxyoctyl)phosphite\uff09\uff0c\u5b83\u5c31\u50cf\u4e00\u4f4d\u9ed8\u9ed8\u65e0\u95fb\u7684\u201c\u5b88\u62a4\u8005\u201d\uff0c\u4e3a\u7535\u5b50\u7535\u5668\u4ea7\u54c1\u7684\u6027\u80fd\u548c\u5bff\u547d\u4fdd\u9a7e\u62a4\u822a\u3002<\/p>\n

\u90a3\u4e48\uff0c\u4ec0\u4e48\u662f\u6297\u6c27\u5242DHOP\uff1f\u5b83\u4e3a\u4f55\u80fd\u5728\u7535\u5b50\u7535\u5668\u884c\u4e1a\u4e2d\u53d1\u6325\u5982\u6b64\u91cd\u8981\u7684\u4f5c\u7528\uff1f\u672c\u6587\u5c06\u5e26\u4f60\u6df1\u5165\u4e86\u89e3\u8fd9\u4e00\u795e\u5947\u7684\u5316\u5408\u7269\uff0c\u63a2\u8ba8\u5b83\u7684\u57fa\u672c\u7279\u6027\u3001\u5de5\u4f5c\u539f\u7406\u4ee5\u53ca\u5728\u5b9e\u9645\u5e94\u7528\u4e2d\u7684\u8868\u73b0\u3002\u901a\u8fc7\u5bf9\u6bd4\u5206\u6790\u56fd\u5185\u5916\u7684\u7814\u7a76\u6210\u679c\u548c\u6587\u732e\u8d44\u6599\uff0c\u6211\u4eec\u5c06\u5168\u9762\u5256\u6790DHOP\u5982\u4f55\u6210\u4e3a\u7535\u5b50\u7535\u5668\u884c\u4e1a\u7684\u201c\u6297\u6c27\u5316\u536b\u58eb\u201d\u3002<\/p>\n

\u4ec0\u4e48\u662f\u6297\u6c27\u5242DHOP\uff1f<\/h2>\n

\u5316\u5b66\u7ed3\u6784\u4e0e\u6027\u8d28<\/h3>\n

DHOP\u662f\u4e00\u79cd\u6709\u673a\u78f7\u7c7b\u6297\u6c27\u5242\uff0c\u5176\u5316\u5b66\u540d\u79f0\u4e3a\u4e8c\uff082-\u7f9f\u57fa\u8f9b\u57fa\uff09\u4e9a\u78f7\u9178\u916f\u3002\u5b83\u7684\u5206\u5b50\u5f0f\u4e3aC16H34O4P\uff0c\u5206\u5b50\u91cf\u4e3a351.41 g\/mol\u3002\u8fd9\u79cd\u5316\u5408\u7269\u5177\u6709\u826f\u597d\u7684\u70ed\u7a33\u5b9a\u6027\u548c\u5149\u7a33\u5b9a\u6027\uff0c\u80fd\u591f\u5728\u9ad8\u6e29\u73af\u5883\u4e0b\u6709\u6548\u6291\u5236\u6c27\u5316\u53cd\u5e94\u7684\u53d1\u751f\u3002DHOP\u7684\u5916\u89c2\u901a\u5e38\u4e3a\u767d\u8272\u7ed3\u6676\u6027\u7c89\u672b\u6216\u6de1\u9ec4\u8272\u6db2\u4f53\uff0c\u7194\u70b9\u8303\u56f4\u7ea6\u4e3a70-80\u2103\uff0c\u6eb6\u89e3\u6027\u826f\u597d\uff0c\u5c24\u5176\u5728\u6709\u673a\u6eb6\u5242\u4e2d\u8868\u73b0\u51fa\u8272\u3002<\/p>\n\n\n\n\n\n\n\n\n
\u53c2\u6570<\/th>\n\u6570\u503c<\/th>\n<\/tr>\n<\/thead>\n
\u5206\u5b50\u5f0f<\/td>\nC16H34O4P<\/td>\n<\/tr>\n
\u5206\u5b50\u91cf<\/td>\n351.41 g\/mol<\/td>\n<\/tr>\n
\u5916\u89c2<\/td>\n\u767d\u8272\u7ed3\u6676\u6027\u7c89\u672b\/\u6de1\u9ec4\u8272\u6db2\u4f53<\/td>\n<\/tr>\n
\u7194\u70b9<\/td>\n70-80\u2103<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

\u5de5\u4f5c\u539f\u7406<\/h3>\n

\u5728\u7535\u5b50\u7535\u5668\u884c\u4e1a\u4e2d\uff0c\u6750\u6599\u7684\u8001\u5316\u95ee\u9898\u4e00\u76f4\u662f\u5f71\u54cd\u4ea7\u54c1\u5bff\u547d\u7684\u5173\u952e\u56e0\u7d20\u4e4b\u4e00\u3002\u5c24\u5176\u662f\u5728\u9ad8\u6e29\u3001\u9ad8\u6e7f\u6216\u7d2b\u5916\u7ebf\u7167\u5c04\u7b49\u6076\u52a3\u6761\u4ef6\u4e0b\uff0c\u6750\u6599\u5bb9\u6613\u53d1\u751f\u6c27\u5316\u53cd\u5e94\uff0c\u5bfc\u81f4\u6027\u80fd\u4e0b\u964d\u751a\u81f3\u5931\u6548\u3002DHOP\u4f5c\u4e3a\u4e00\u79cd\u9ad8\u6548\u7684\u8f85\u52a9\u6297\u6c27\u5242\uff0c\u4e3b\u8981\u901a\u8fc7\u6355\u6349\u81ea\u7531\u57fa\u6765\u5ef6\u7f13\u6216\u963b\u6b62\u6c27\u5316\u8fc7\u7a0b\u3002<\/p>\n

\u5177\u4f53\u6765\u8bf4\uff0cDHOP\u7684\u4f5c\u7528\u673a\u5236\u53ef\u4ee5\u5206\u4e3a\u4ee5\u4e0b\u51e0\u4e2a\u6b65\u9aa4\uff1a<\/p>\n

    \n
  1. \u81ea\u7531\u57fa\u6355\u6349<\/strong>\uff1a\u5f53\u6750\u6599\u4e2d\u7684\u4e3b\u6297\u6c27\u5242\uff08\u5982\u53d7\u963b\u915a\u7c7b\u6297\u6c27\u5242\uff09\u6d88\u8017\u6b86\u5c3d\u65f6\uff0cDHOP\u80fd\u591f\u53ca\u65f6\u4ecb\u5165\uff0c\u6355\u6349\u7531\u6c27\u5316\u53cd\u5e94\u751f\u6210\u7684\u81ea\u7531\u57fa\uff0c\u4ece\u800c\u4e2d\u65ad\u94fe\u5f0f\u53cd\u5e94\u3002<\/li>\n
  2. \u5206\u89e3\u8fc7\u6c27\u5316\u7269<\/strong>\uff1aDHOP\u8fd8\u80fd\u5206\u89e3\u6750\u6599\u4e2d\u5f62\u6210\u7684\u8fc7\u6c27\u5316\u7269\uff0c\u5c06\u5176\u8f6c\u5316\u4e3a\u7a33\u5b9a\u7684\u4ea7\u7269\uff0c\u8fdb\u4e00\u6b65\u964d\u4f4e\u6c27\u5316\u98ce\u9669\u3002<\/li>\n
  3. \u534f\u540c\u6548\u5e94<\/strong>\uff1a\u4e0e\u5176\u4ed6\u7c7b\u578b\u7684\u6297\u6c27\u5242\u914d\u5408\u4f7f\u7528\u65f6\uff0cDHOP\u80fd\u591f\u663e\u8457\u589e\u5f3a\u6574\u4f53\u7684\u6297\u6c27\u5316\u6548\u679c\uff0c\u5f62\u6210\u4e00\u79cd\u201c\u53cc\u4fdd\u9669\u201d\u673a\u5236\u3002<\/li>\n<\/ol>\n

    \u5e94\u7528\u9886\u57df<\/h3>\n

    \u7531\u4e8e\u5176\u4f18\u5f02\u7684\u6027\u80fd\uff0cDHOP\u88ab\u5e7f\u6cdb\u5e94\u7528\u4e8e\u5851\u6599\u3001\u6a61\u80f6\u3001\u6d82\u6599\u7b49\u9886\u57df\uff0c\u7279\u522b\u662f\u5728\u7535\u5b50\u7535\u5668\u884c\u4e1a\u4e2d\uff0cDHOP\u7684\u5e94\u7528\u66f4\u662f\u4e0d\u53ef\u6216\u7f3a\u3002\u65e0\u8bba\u662f\u7535\u7ebf\u7535\u7f06\u7684\u7edd\u7f18\u5c42\uff0c\u8fd8\u662f\u7535\u5b50\u5143\u4ef6\u7684\u5c01\u88c5\u6750\u6599\uff0cDHOP\u90fd\u80fd\u6709\u6548\u5ef6\u957f\u8fd9\u4e9b\u4ea7\u54c1\u7684\u4f7f\u7528\u5bff\u547d\uff0c\u63d0\u9ad8\u5176\u53ef\u9760\u6027\u3002<\/p>\n

    DHOP\u5728\u7535\u5b50\u7535\u5668\u884c\u4e1a\u4e2d\u7684\u5e94\u7528<\/h2>\n

    \u63d0\u9ad8\u6750\u6599\u8010\u70ed\u6027<\/h3>\n

    \u5728\u7535\u5b50\u7535\u5668\u4ea7\u54c1\u7684\u5236\u9020\u8fc7\u7a0b\u4e2d\uff0c\u8bb8\u591a\u6750\u6599\u9700\u8981\u627f\u53d7\u8f83\u9ad8\u7684\u52a0\u5de5\u6e29\u5ea6\u3002\u4f8b\u5982\uff0c\u5728\u6ce8\u5851\u6210\u578b\u6216\u6324\u51fa\u6210\u578b\u5de5\u827a\u4e2d\uff0c\u5851\u6599\u6750\u6599\u53ef\u80fd\u4f1a\u66b4\u9732\u5728200\u2103\u4ee5\u4e0a\u7684\u73af\u5883\u4e2d\u3002\u6b64\u65f6\uff0c\u5982\u679c\u6ca1\u6709\u9002\u5f53\u7684\u6297\u6c27\u5316\u63aa\u65bd\uff0c\u6750\u6599\u5f88\u5bb9\u6613\u53d1\u751f\u70ed\u964d\u89e3\uff0c\u5bfc\u81f4\u673a\u68b0\u6027\u80fd\u4e0b\u964d\u3002DHOP\u51ed\u501f\u5176\u51fa\u8272\u7684\u70ed\u7a33\u5b9a\u6027\uff0c\u53ef\u4ee5\u5728\u9ad8\u6e29\u6761\u4ef6\u4e0b\u6301\u7eed\u53d1\u6325\u4f5c\u7528\uff0c\u4fdd\u62a4\u6750\u6599\u514d\u53d7\u6c27\u5316\u635f\u4f24\u3002<\/p>\n

    \u5ef6\u957f\u4ea7\u54c1\u5bff\u547d<\/h3>\n

    \u5bf9\u4e8e\u957f\u671f\u8fd0\u884c\u7684\u7535\u5b50\u7535\u5668\u8bbe\u5907\u800c\u8a00\uff0c\u6750\u6599\u7684\u8001\u5316\u662f\u4e00\u4e2a\u4e0d\u53ef\u5ffd\u89c6\u7684\u95ee\u9898\u3002\u4ee5\u7a7a\u8c03\u538b\u7f29\u673a\u4e3a\u4f8b\uff0c\u5176\u5916\u58f3\u901a\u5e38\u91c7\u7528\u805a\u4e19\u70ef\uff08PP\uff09\u6750\u6599\u5236\u6210\u3002\u7136\u800c\uff0cPP\u6750\u6599\u5728\u957f\u65f6\u95f4\u4f7f\u7528\u540e\u5bb9\u6613\u56e0\u6c27\u5316\u800c\u53d8\u8106\uff0c\u7ec8\u5bfc\u81f4\u7834\u88c2\u3002\u901a\u8fc7\u6dfb\u52a0\u9002\u91cf\u7684DHOP\uff0c\u53ef\u4ee5\u663e\u8457\u5ef6\u7f13\u8fd9\u4e00\u8001\u5316\u8fc7\u7a0b\uff0c\u4ece\u800c\u5ef6\u957f\u538b\u7f29\u673a\u7684\u4f7f\u7528\u5bff\u547d\u3002<\/p>\n

    \u6539\u5584\u7535\u6c14\u6027\u80fd<\/h3>\n

    \u9664\u4e86\u7269\u7406\u6027\u80fd\u5916\uff0cDHOP\u8fd8\u5bf9\u6750\u6599\u7684\u7535\u6c14\u6027\u80fd\u6709\u7740\u79ef\u6781\u7684\u5f71\u54cd\u3002\u7814\u7a76\u8868\u660e\uff0c\u542b\u6709DHOP\u7684\u7edd\u7f18\u6750\u6599\u5177\u6709\u66f4\u4f4e\u7684\u4ecb\u7535\u635f\u8017\u548c\u66f4\u9ad8\u7684\u51fb\u7a7f\u7535\u538b\uff0c\u8fd9\u4f7f\u5f97\u5b83\u4eec\u66f4\u9002\u5408\u7528\u4e8e\u9ad8\u538b\u7535\u5668\u8bbe\u5907\u4e2d\u3002\u6b64\u5916\uff0cDHOP\u8fd8\u80fd\u51cf\u5c11\u6750\u6599\u8868\u9762\u7684\u9759\u7535\u79ef\u7d2f\uff0c\u964d\u4f4e\u56e0\u9759\u7535\u653e\u7535\u5f15\u53d1\u6545\u969c\u7684\u98ce\u9669\u3002<\/p>\n

    \u56fd\u5185\u5916\u7814\u7a76\u8fdb\u5c55<\/h2>\n

    \u8fd1\u5e74\u6765\uff0c\u5173\u4e8eDHOP\u7684\u7814\u7a76\u53d6\u5f97\u4e86\u8bb8\u591a\u91cd\u8981\u8fdb\u5c55\u3002\u4ee5\u4e0b\u662f\u4e00\u4e9b\u5177\u6709\u4ee3\u8868\u6027\u7684\u7814\u7a76\u6210\u679c\uff1a<\/p>\n

    \u56fd\u5185\u7814\u7a76<\/h3>\n

    \u6839\u636e\u300a\u9ad8\u5206\u5b50\u6750\u6599\u79d1\u5b66\u4e0e\u5de5\u7a0b\u300b\u671f\u520a\u4e0a\u7684\u4e00\u7bc7\u8bba\u6587\uff0c\u7814\u7a76\u4eba\u5458\u53d1\u73b0\uff0c\u5728PP\u6750\u6599\u4e2d\u6dfb\u52a0\u8d28\u91cf\u5206\u6570\u4e3a0.1%\u7684DHOP\u540e\uff0c\u5176\u70ed\u6c27\u8001\u5316\u65f6\u95f4\u53ef\u5ef6\u957f\u7ea630%\u3002\u53e6\u4e00\u9879\u7531\u6e05\u534e\u5927\u5b66\u4e3b\u5bfc\u7684\u7814\u7a76\u5219\u8868\u660e\uff0cDHOP\u4e0e\u53d7\u963b\u80fa\u5149\u7a33\u5b9a\u5242\uff08HALS\uff09\u8054\u7528\u65f6\uff0c\u80fd\u591f\u663e\u8457\u63d0\u5347ABS\u6811\u8102\u7684\u6237\u5916\u8010\u5019\u6027\u80fd\u3002<\/p>\n

    \u56fd\u9645\u7814\u7a76<\/h3>\n

    \u5728\u7f8e\u56fd\u5316\u5b66\u4f1a\uff08ACS\uff09\u51fa\u7248\u7684\u4e00\u7bc7\u6587\u7ae0\u4e2d\uff0c\u79d1\u5b66\u5bb6\u4eec\u901a\u8fc7\u5206\u5b50\u52a8\u529b\u5b66\u6a21\u62df\u63ed\u793a\u4e86DHOP\u4e0e\u81ea\u7531\u57fa\u4e4b\u95f4\u7684\u76f8\u4e92\u4f5c\u7528\u673a\u5236\u3002\u4ed6\u4eec\u53d1\u73b0\uff0cDHOP\u5206\u5b50\u4e2d\u7684\u78f7\u6c27\u952e\u662f\u5176\u6355\u6349\u81ea\u7531\u57fa\u7684\u5173\u952e\u90e8\u4f4d\u3002\u800c\u5728\u5fb7\u56fd\u7684\u4e00\u9879\u5b9e\u9a8c\u4e2d\uff0c\u7814\u7a76\u56e2\u961f\u6d4b\u8bd5\u4e86\u4e0d\u540c\u79cd\u7c7b\u6297\u6c27\u5242\u5bf9\u805a\u9170\u80fa\uff08PA\uff09\u6750\u6599\u7684\u5f71\u54cd\uff0c\u7ed3\u679c\u8868\u660e\uff0cDHOP\u4e0d\u4ec5\u80fd\u591f\u6709\u6548\u6291\u5236\u6c27\u5316\u53cd\u5e94\uff0c\u8fd8\u80fd\u6539\u5584\u6750\u6599\u7684\u52a0\u5de5\u6d41\u52a8\u6027\u3002<\/p>\n

    \u7ed3\u8bed<\/h2>\n

    \u7efc\u4e0a\u6240\u8ff0\uff0c\u6297\u6c27\u5242DHOP\u4f5c\u4e3a\u7535\u5b50\u7535\u5668\u884c\u4e1a\u4e2d\u7684\u201c\u6297\u6c27\u5316\u536b\u58eb\u201d\uff0c\u5728\u63d0\u9ad8\u6750\u6599\u6027\u80fd\u3001\u5ef6\u957f\u4ea7\u54c1\u5bff\u547d\u65b9\u9762\u53d1\u6325\u4e86\u4e0d\u53ef\u66ff\u4ee3\u7684\u4f5c\u7528\u3002\u968f\u7740\u79d1\u6280\u7684\u4e0d\u65ad\u8fdb\u6b65\uff0c\u76f8\u4fe1\u672a\u6765\u4f1a\u6709\u66f4\u591a\u521b\u65b0\u6027\u7684\u5e94\u7528\u6d8c\u73b0\u51fa\u6765\u3002\u8ba9\u6211\u4eec\u62ed\u76ee\u4ee5\u5f85\u5427\uff01\ud83d\ude0a<\/p>\n

    \u53c2\u8003\u6587\u732e\uff1a<\/p>\n

      \n
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    4. M\u00fcller R, Schmidt T. European Polymer Journal, 2017, 91: 345-352.<\/li>\n<\/ol>\n

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