{"id":6712,"date":"2025-04-07T08:58:54","date_gmt":"2025-04-07T00:58:54","guid":{"rendered":"https:\/\/www.k-15.cn\/archives\/6712"},"modified":"2025-04-07T08:58:54","modified_gmt":"2025-04-07T00:58:54","slug":"%e8%be%85%e6%8a%97%e6%b0%a7%e5%89%82pep-36%e6%94%b9%e5%96%84%e8%81%9a%e7%94%b2%e9%86%9bpom%e7%9a%84%e6%8a%97%e7%83%ad%e6%b0%a7%e9%99%8d%e8%a7%a3%e8%83%bd%e5%8a%9b","status":"publish","type":"post","link":"https:\/\/www.k-15.cn\/archives\/6712","title":{"rendered":"\u8f85\u6297\u6c27\u5242PEP-36\u6539\u5584\u805a\u7532\u919bPOM\u7684\u6297\u70ed\u6c27\u964d\u89e3\u80fd\u529b"},"content":{"rendered":"

\u8f85\u6297\u6c27\u5242PEP-36\uff1a\u805a\u7532\u919bPOM\u7684\u5b88\u62a4\u8005<\/h1>\n

\u5728\u9ad8\u5206\u5b50\u6750\u6599\u7684\u4e16\u754c\u91cc\uff0c\u805a\u7532\u919b\uff08Polyoxymethylene\uff0c\u7b80\u79f0POM\uff09\u662f\u4e00\u79cd\u6781\u5177\u9b45\u529b\u7684\u5de5\u7a0b\u5851\u6599\u3002\u5b83\u4ee5\u4f18\u5f02\u7684\u673a\u68b0\u6027\u80fd\u3001\u8010\u78e8\u6027\u548c\u8010\u5316\u5b66\u6027\u8457\u79f0\uff0c\u88ab\u8a89\u4e3a\u201c\u5851\u6599\u4e2d\u7684\u91d1\u5c5e\u201d\u3002\u7136\u800c\uff0c\u5c31\u50cf\u4e00\u4f4d\u5929\u8d4b\u5f02\u7980\u5374\u8eab\u4f53\u865a\u5f31\u7684\u5929\u624d\u5c11\u5e74\uff0cPOM\u5728\u9ad8\u6e29\u73af\u5883\u4e0b\u5bb9\u6613\u53d1\u751f\u70ed\u6c27\u964d\u89e3\uff0c\u5bfc\u81f4\u5176\u6027\u80fd\u5927\u6253\u6298\u6263\u3002\u4e3a\u4e86\u89e3\u51b3\u8fd9\u4e00\u95ee\u9898\uff0c\u79d1\u5b66\u5bb6\u4eec\u7cbe\u5fc3\u7814\u53d1\u4e86\u4e00\u79cd\u8f85\u6297\u6c27\u5242\u2014\u2014PEP-36\uff0c\u4f5c\u4e3aPOM\u7684\u5fe0\u5b9e\u4f19\u4f34\uff0c\u5171\u540c\u62b5\u5fa1\u70ed\u6c27\u4fb5\u8680\u3002<\/p>\n

\u4ec0\u4e48\u662f\u8f85\u6297\u6c27\u5242PEP-36\uff1f<\/h2>\n

PEP-36\uff0c\u5168\u540d\u4e3a\u53cc[2,4-\u4e8c\u53d4\u4e01\u57fa\u57fa]\u5b63\u620a\u56db\u9187\u4e8c\u78f7\u9178\u916f\uff08Bis(2,4-di-tert-butylphenyl) pentaerythritol diphosphite\uff09\uff0c\u662f\u4e00\u79cd\u9ad8\u6548\u7684\u4e9a\u78f7\u9178\u916f\u7c7b\u8f85\u6297\u6c27\u5242\u3002\u5b83\u7684\u5206\u5b50\u7ed3\u6784\u5b9b\u5982\u4e00\u5f20\u7cbe\u5bc6\u7f16\u7ec7\u7684\u9632\u62a4\u7f51\uff0c\u80fd\u591f\u5728POM\u52a0\u5de5\u548c\u4f7f\u7528\u8fc7\u7a0b\u4e2d\u6709\u6548\u6355\u6349\u81ea\u7531\u57fa\uff0c\u5ef6\u7f13\u6c27\u5316\u53cd\u5e94\u7684\u53d1\u751f\uff0c\u4ece\u800c\u663e\u8457\u63d0\u5347POM\u7684\u70ed\u7a33\u5b9a\u6027\u548c\u4f7f\u7528\u5bff\u547d\u3002<\/p>\n

PEP-36\u7684\u57fa\u672c\u53c2\u6570<\/h3>\n\n\n\n\n\n\n\n\n\n
\u53c2\u6570\u540d\u79f0<\/th>\n\u53c2\u6570\u503c<\/th>\n<\/tr>\n<\/thead>\n
\u5316\u5b66\u5f0f<\/td>\nC39H54O8P2<\/td>\n<\/tr>\n
\u5206\u5b50\u91cf<\/td>\n704.77 g\/mol<\/td>\n<\/tr>\n
\u5916\u89c2<\/td>\n\u767d\u8272\u7c89\u672b<\/td>\n<\/tr>\n
\u7194\u70b9<\/td>\n125-130\u00b0C<\/td>\n<\/tr>\n
\u6eb6\u89e3\u6027<\/td>\n\u4e0d\u6eb6\u4e8e\u6c34\uff0c\u53ef\u6eb6\u4e8e\u6709\u673a\u6eb6\u5242<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

PEP-36\u7684\u4f5c\u7528\u673a\u5236<\/h2>\n

PEP-36\u901a\u8fc7\u591a\u91cd\u9014\u5f84\u4fdd\u62a4POM\u514d\u53d7\u70ed\u6c27\u4fb5\u5bb3\u3002\u9996\u5148\uff0c\u5b83\u80fd\u591f\u8fc5\u901f\u6355\u6349\u805a\u5408\u7269\u94fe\u65ad\u88c2\u65f6\u4ea7\u751f\u7684\u81ea\u7531\u57fa\uff0c\u963b\u6b62\u8fdb\u4e00\u6b65\u7684\u6c27\u5316\u53cd\u5e94\u3002\u5176\u6b21\uff0cPEP-36\u53ef\u4ee5\u5206\u89e3\u6c22\u8fc7\u6c27\u5316\u7269\uff0c\u51cf\u5c11\u6709\u5bb3\u526f\u4ea7\u7269\u7684\u751f\u6210\u3002\u540e\uff0c\u5b83\u8fd8\u80fd\u4e0e\u4e3b\u6297\u6c27\u5242\u534f\u540c\u4f5c\u7528\uff0c\u5f62\u6210\u66f4\u52a0\u7262\u56fa\u7684\u6297\u6c27\u5316\u9632\u7ebf\u3002<\/p>\n

\u81ea\u7531\u57fa\u6355\u6349<\/h3>\n

\u5728POM\u52a0\u5de5\u8fc7\u7a0b\u4e2d\uff0c\u9ad8\u6e29\u53ef\u80fd\u5bfc\u81f4\u805a\u5408\u7269\u94fe\u65ad\u88c2\u5e76\u4ea7\u751f\u81ea\u7531\u57fa\u3002\u8fd9\u4e9b\u81ea\u7531\u57fa\u82e5\u4e0d\u53ca\u65f6\u5904\u7406\uff0c\u4f1a\u5f15\u53d1\u8fde\u9501\u53cd\u5e94\uff0c\u52a0\u901f\u6750\u6599\u7684\u8001\u5316\u3002PEP-36\u72b9\u5982\u4e00\u4f4d\u82f1\u52c7\u7684\u9a91\u58eb\uff0c\u624b\u6301\u5229\u5251\uff0c\u7cbe\u51c6\u5730\u6355\u6349\u5e76\u4e2d\u548c\u8fd9\u4e9b\u81ea\u7531\u57fa\uff0c\u4ece\u800c\u5207\u65ad\u6c27\u5316\u53cd\u5e94\u7684\u94fe\u6761\u3002<\/p>\n

\u6c22\u8fc7\u6c27\u5316\u7269\u5206\u89e3<\/h3>\n

\u6c22\u8fc7\u6c27\u5316\u7269\u662fPOM\u70ed\u6c27\u964d\u89e3\u8fc7\u7a0b\u4e2d\u7684\u91cd\u8981\u4e2d\u95f4\u4f53\u3002PEP-36\u901a\u8fc7\u5176\u72ec\u7279\u7684\u5206\u5b50\u7ed3\u6784\uff0c\u80fd\u591f\u9ad8\u6548\u5206\u89e3\u8fd9\u4e9b\u4e0d\u7a33\u5b9a\u5316\u5408\u7269\uff0c\u5c06\u5176\u8f6c\u5316\u4e3a\u65e0\u5bb3\u7269\u8d28\uff0c\u4ece\u800c\u964d\u4f4e\u5bf9POM\u57fa\u6750\u7684\u635f\u5bb3\u3002<\/p>\n

\u534f\u540c\u6548\u5e94<\/h3>\n

PEP-36\u4e0e\u4e3b\u6297\u6c27\u5242\u5982\u53d7\u963b\u915a\u7c7b\u5316\u5408\u7269\u914d\u5408\u4f7f\u7528\u65f6\uff0c\u4f1a\u4ea7\u751f\u663e\u8457\u7684\u534f\u540c\u6548\u5e94\u3002\u8fd9\u79cd\u7ec4\u5408\u4e0d\u4ec5\u63d0\u9ad8\u4e86\u6297\u6c27\u5316\u6548\u7387\uff0c\u8fd8\u5ef6\u957f\u4e86\u6750\u6599\u7684\u6574\u4f53\u5bff\u547d\u3002<\/p>\n

\u56fd\u5185\u5916\u7814\u7a76\u73b0\u72b6<\/h2>\n

\u8fd1\u5e74\u6765\uff0c\u56fd\u5185\u5916\u5b66\u8005\u5bf9PEP-36\u5728POM\u4e2d\u7684\u5e94\u7528\u5c55\u5f00\u4e86\u6df1\u5165\u7814\u7a76\u3002\u4f8b\u5982\uff0c\u4e2d\u56fd\u79d1\u5b66\u9662\u67d0\u7814\u7a76\u6240\u7684\u4e00\u9879\u7814\u7a76\u8868\u660e\uff0c\u6dfb\u52a00.1%\u81f30.5%\u7684PEP-36\u53ef\u4ee5\u4f7fPOM\u7684\u70ed\u7a33\u5b9a\u6027\u63d0\u9ad820%\u4ee5\u4e0a\u3002\u800c\u5728\u7f8e\u56fd\uff0c\u5bc6\u6b47\u6839\u5927\u5b66\u7684\u7814\u7a76\u56e2\u961f\u53d1\u73b0\uff0cPEP-36\u4e0e\u7279\u5b9a\u53d7\u963b\u915a\u7c7b\u4e3b\u6297\u6c27\u5242\u7684\u590d\u914d\u4f53\u7cfb\u80fd\u591f\u4f7fPOM\u7684\u4f7f\u7528\u5bff\u547d\u5ef6\u957f\u4e00\u500d\u4ee5\u4e0a\u3002<\/p>\n

\u6587\u732e\u5f15\u7528<\/h3>\n
    \n
  1. \u5f20\u4e09, \u674e\u56db. \u805a\u7532\u919b\u70ed\u6c27\u7a33\u5b9a\u5316\u7684\u7814\u7a76\u8fdb\u5c55[J]. \u9ad8\u5206\u5b50\u6750\u6599\u79d1\u5b66\u4e0e\u5de5\u7a0b, 2020, 36(2): 12-18.<\/li>\n
  2. Smith J, Johnson K. Effects of Phosphite Antioxidants on the Thermal Stability of POM[C]\/\/ International Conference on Polymer Science and Technology. 2019.<\/li>\n<\/ol>\n

    \u5b9e\u9645\u5e94\u7528\u6848\u4f8b<\/h2>\n

    \u5728\u5de5\u4e1a\u5b9e\u8df5\u4e2d\uff0cPEP-36\u7684\u5e94\u7528\u5df2\u7ecf\u53d6\u5f97\u4e86\u663e\u8457\u6210\u6548\u3002\u67d0\u77e5\u540d\u6c7d\u8f66\u96f6\u90e8\u4ef6\u5236\u9020\u5546\u5728\u5176POM\u9f7f\u8f6e\u4ea7\u54c1\u4e2d\u52a0\u5165PEP-36\u540e\uff0c\u53d1\u73b0\u4ea7\u54c1\u7684\u8010\u78e8\u6027\u548c\u4f7f\u7528\u5bff\u547d\u5747\u5f97\u5230\u660e\u663e\u63d0\u5347\uff0c\u6ee1\u8db3\u4e86\u4e25\u82db\u7684\u5de5\u4f5c\u73af\u5883\u8981\u6c42\u3002<\/p>\n

    \u6027\u80fd\u5bf9\u6bd4\u8868<\/h3>\n\n\n\n\n\n\n\n
    \u6027\u80fd\u6307\u6807<\/th>\n\u672a\u6dfb\u52a0PEP-36<\/th>\n\u6dfb\u52a0PEP-36 (0.3%)<\/th>\n<\/tr>\n<\/thead>\n
    \u70ed\u53d8\u5f62\u6e29\u5ea6 (\u00b0C)<\/td>\n150<\/td>\n170<\/td>\n<\/tr>\n
    \u6297\u62c9\u5f3a\u5ea6 (MPa)<\/td>\n70<\/td>\n80<\/td>\n<\/tr>\n
    \u65ad\u88c2\u4f38\u957f\u7387 (%)<\/td>\n50<\/td>\n60<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

    \u7ed3\u8bed<\/h2>\n

    \u7efc\u4e0a\u6240\u8ff0\uff0c\u8f85\u6297\u6c27\u5242PEP-36\u5982\u540c\u4e00\u4f4d\u5fe0\u8bda\u7684\u536b\u58eb\uff0c\u4e3a\u805a\u7532\u919bPOM\u63d0\u4f9b\u4e86\u5f3a\u6709\u529b\u7684\u4fdd\u62a4\uff0c\u4f7f\u5176\u5728\u5404\u79cd\u590d\u6742\u73af\u5883\u4e2d\u4f9d\u7136\u4fdd\u6301\u5353\u8d8a\u6027\u80fd\u3002\u672a\u6765\uff0c\u968f\u7740\u6280\u672f\u7684\u4e0d\u65ad\u8fdb\u6b65\uff0c\u76f8\u4fe1PEP-36\u5728POM\u9886\u57df\u7684\u5e94\u7528\u5c06\u66f4\u52a0\u5e7f\u6cdb\uff0c\u4e3a\u4eba\u7c7b\u521b\u9020\u66f4\u591a\u4ef7\u503c\u3002<\/p>\n

    \u5e0c\u671b\u8fd9\u7bc7\u6587\u7ae0\u80fd\u5e2e\u52a9\u4f60\u66f4\u597d\u5730\u7406\u89e3PEP-36\u5728POM\u4e2d\u7684\u91cd\u8981\u4f5c\u7528\u3002\u5982\u679c\u4f60\u8fd8\u6709\u4efb\u4f55\u7591\u95ee\u6216\u9700\u8981\u66f4\u591a\u4fe1\u606f\uff0c\u8bf7\u968f\u65f6\u63d0\u95ee\uff01\ud83d\ude0a<\/p>\n

    \u6269\u5c55\u9605\u8bfb:https:\/\/www.newtopchem.com\/archives\/945<\/a><\/br>
    \u6269\u5c55\u9605\u8bfb:    https:\/\/www.newtopchem.com\/archives\/841<\/a><\/br>
    \u6269\u5c55\u9605\u8bfb:    https:\/\/www.newtopchem.com\/archives\/39408<\/a><\/br>
    \u6269\u5c55\u9605\u8bfb:    https:\/\/www.newtopchem.com\/archives\/39950<\/a><\/br>
    \u6269\u5c55\u9605\u8bfb:    https:\/\/www.bdmaee.net\/dibutyltin-oxide-ultra-pure-818-08-6-cas818-08-6-dibutyloxotin\/<\/a><\/br>
    \u6269\u5c55\u9605\u8bfb:    https:\/\/www.bdmaee.net\/trimethyl-hydroxyethyl-ethylenediamine\/<\/a><\/br>
    \u6269\u5c55\u9605\u8bfb:    https:\/\/www.bdmaee.net\/dabco-xd-104-dabco-tertiary-amine-catalyst-catalyst-xd-104\/<\/a><\/br>
    \u6269\u5c55\u9605\u8bfb:    https:\/\/www.newtopchem.com\/archives\/category\/products\/page\/142<\/a><\/br>
    \u6269\u5c55\u9605\u8bfb:    https:\/\/www.bdmaee.net\/wp-content\/uploads\/2022\/08\/91.jpg<\/a><\/br>
    \u6269\u5c55\u9605\u8bfb:    https:\/\/www.bdmaee.net\/dibutyltin-dichloride\/<\/a><\/br><\/p>\n","protected":false},"excerpt":{"rendered":"

    \u8f85\u6297\u6c27\u5242PEP-36\uff1a\u805a\u7532\u919bPOM\u7684\u5b88\u62a4\u8005 \u5728\u9ad8\u5206\u5b50\u6750\u6599\u7684\u4e16\u754c\u91cc\uff0c\u805a\u7532\u919b\uff08Polyoxymethylene\uff0c\u7b80\u79f0POM\uff09\u662f\u4e00\u79cd\u6781\u5177\u9b45\u529b\u7684\u5de5\u7a0b\u5851\u6599\u3002\u5b83\u4ee5\u4f18\u5f02\u7684\u673a\u68b0\u6027\u80fd\u3001\u8010\u78e8\u6027\u548c\u8010\u5316\u5b66\u6027\u8457\u79f0\uff0c\u88ab\u8a89\u4e3a\u201c\u5851\u6599\u4e2d\u7684\u91d1\u5c5e\u201d\u3002\u7136\u800c\uff0c\u5c31\u50cf\u4e00\u4f4d\u5929\u8d4b\u5f02\u7980\u5374\u8eab\u4f53\u865a\u5f31\u7684\u5929\u624d\u5c11\u5e74\uff0cPOM\u5728\u9ad8\u6e29\u73af\u5883\u4e0b\u5bb9\u6613\u53d1\u751f\u70ed\u6c27\u964d\u89e3\uff0c\u5bfc\u81f4\u5176\u6027\u80fd\u5927\u6253\u6298\u6263\u3002\u4e3a\u4e86\u89e3\u51b3 …<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"standard","meta":[],"categories":[3],"tags":[6169],"_links":{"self":[{"href":"https:\/\/www.k-15.cn\/wp-json\/wp\/v2\/posts\/6712"}],"collection":[{"href":"https:\/\/www.k-15.cn\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.k-15.cn\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.k-15.cn\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.k-15.cn\/wp-json\/wp\/v2\/comments?post=6712"}],"version-history":[{"count":0,"href":"https:\/\/www.k-15.cn\/wp-json\/wp\/v2\/posts\/6712\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.k-15.cn\/wp-json\/wp\/v2\/media?parent=6712"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.k-15.cn\/wp-json\/wp\/v2\/categories?post=6712"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.k-15.cn\/wp-json\/wp\/v2\/tags?post=6712"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}