\u5728\u9ad8\u5206\u5b50\u6750\u6599\u7684\u4e16\u754c\u91cc\uff0c\u805a\u916f\u5f39\u6027\u4f53\uff08TPEE\uff09\u88ab\u8a89\u4e3a\u201c\u5851\u6599\u754c\u7684\u5168\u80fd\u9009\u624b\u201d\u3002\u5b83\u65e2\u6709\u6a61\u80f6\u7684\u67d4\u8f6f\u6027\uff0c\u53c8\u6709\u5851\u6599\u7684\u5f3a\u5ea6\u548c\u8010\u70ed\u6027\uff0c\u582a\u79f0\u6027\u80fd\u4e0e\u529f\u80fd\u7684\u5b8c\u7f8e\u7ed3\u5408\u3002\u7136\u800c\uff0c\u5728\u5b9e\u9645\u52a0\u5de5\u8fc7\u7a0b\u4e2d\uff0cTPEE\u5374\u5e38\u5e38\u9762\u4e34\u4e00\u4e2a\u81f4\u547d\u7684\u95ee\u9898\u2014\u2014\u70ed\u964d\u89e3\u3002\u8fd9\u5c31\u50cf\u4e00\u4f4d\u624d\u534e\u6a2a\u6ea2\u7684\u827a\u672f\u5bb6\uff0c\u5728\u521b\u4f5c\u8fc7\u7a0b\u4e2d\u5374\u56e0\u73af\u5883\u9650\u5236\u800c\u65e0\u6cd5\u5c3d\u60c5\u53d1\u6325\u3002\u5e78\u8fd0\u7684\u662f\uff0c\u8f85\u6297\u6c27\u5242PEP-36\u5982\u540c\u4e00\u4f4d\u8d34\u5fc3\u7684\u52a9\u624b\uff0c\u4e3aTPEE\u63d0\u4f9b\u4e86\u5f3a\u6709\u529b\u7684\u4fdd\u62a4\uff0c\u8ba9\u5176\u5728\u52a0\u5de5\u4e2d\u4fdd\u6301\u7a33\u5b9a\u3001\u6301\u4e45\u7684\u6027\u80fd\u3002<\/p>\n
\u672c\u6587\u5c06\u6df1\u5165\u63a2\u8ba8PEP-36\u5728TPEE\u52a0\u5de5\u4e2d\u7684\u4f5c\u7528\u673a\u5236\uff0c\u5206\u6790\u5176\u4ea7\u54c1\u53c2\u6570\u53ca\u5e94\u7528\u573a\u666f\uff0c\u5e76\u901a\u8fc7\u56fd\u5185\u5916\u6587\u732e\u652f\u6301\uff0c\u4e3a\u8bfb\u8005\u5448\u73b0\u4e00\u5e45\u5b8c\u6574\u7684\u201c\u6297\u6c27\u9632\u62a4\u56fe\u8c31\u201d\u3002<\/p>\n
TPEE\u662f\u4e00\u79cd\u7531\u786c\u6bb5\u548c\u8f6f\u6bb5\u4ea4\u66ff\u7ec4\u6210\u7684\u5d4c\u6bb5\u5171\u805a\u7269\uff0c\u517c\u5177\u70ed\u5851\u6027\u548c\u5f39\u6027\u4f53\u7684\u53cc\u91cd\u4f18\u52bf\u3002\u5176\u4e3b\u8981\u6210\u5206\u5305\u62ec\u82b3\u9999\u65cf\u4e8c\u5143\u9178\u3001\u8102\u80aa\u65cf\u4e8c\u9187\u4ee5\u53ca\u6269\u94fe\u5242\u7b49\u3002\u8fd9\u4e9b\u6210\u5206\u8d4b\u4e88\u4e86TPEE\u5353\u8d8a\u7684\u673a\u68b0\u6027\u80fd\u3001\u8010\u78e8\u6027\u548c\u8010\u5316\u5b66\u8150\u8680\u80fd\u529b\uff0c\u4f7f\u5176\u5e7f\u6cdb\u5e94\u7528\u4e8e\u6c7d\u8f66\u96f6\u90e8\u4ef6\u3001\u5de5\u4e1a\u8bbe\u5907\u3001\u8fd0\u52a8\u5668\u6750\u7b49\u9886\u57df\u3002<\/p>\n
\u7136\u800c\uff0cTPEE\u5728\u9ad8\u6e29\u52a0\u5de5\u6761\u4ef6\u4e0b\u7684\u7a33\u5b9a\u6027\u5374\u4ee4\u4eba\u62c5\u5fe7\u3002\u5728\u6324\u51fa\u3001\u6ce8\u5851\u7b49\u5de5\u827a\u4e2d\uff0c\u6e29\u5ea6\u901a\u5e38\u9ad8\u8fbe200\u00b0C\u4ee5\u4e0a\uff0c\u6b64\u65f6TPEE\u5206\u5b50\u94fe\u5bb9\u6613\u53d1\u751f\u6c27\u5316\u964d\u89e3\u53cd\u5e94\uff0c\u5bfc\u81f4\u6750\u6599\u6027\u80fd\u4e0b\u964d\u751a\u81f3\u5931\u6548\u3002\u8fd9\u79cd\u73b0\u8c61\u4e0d\u4ec5\u5f71\u54cd\u4ea7\u54c1\u8d28\u91cf\uff0c\u8fd8\u4f1a\u589e\u52a0\u751f\u4ea7\u6210\u672c\u3002<\/p>\n
\u8f85\u6297\u6c27\u5242PEP-36\uff08Phosphite Ester Polymerization Product\uff09\uff0c\u5373\u4e9a\u78f7\u9178\u4e09\u916f\u7c7b\u5316\u5408\u7269\uff0c\u662f\u4e00\u79cd\u9ad8\u6548\u7684\u6297\u6c27\u5316\u52a9\u5242\u3002\u5b83\u7684\u4e3b\u8981\u529f\u80fd\u662f\u6355\u83b7\u81ea\u7531\u57fa\uff0c\u6291\u5236\u6c27\u5316\u53cd\u5e94\u7684\u53d1\u751f\uff0c\u4ece\u800c\u5ef6\u957f\u6750\u6599\u7684\u4f7f\u7528\u5bff\u547d\u3002\u5177\u4f53\u6765\u8bf4\uff0cPEP-36\u901a\u8fc7\u4ee5\u4e0b\u51e0\u79cd\u65b9\u5f0f\u53d1\u6325\u4f5c\u7528\uff1a<\/p>\n
\u7528\u4e00\u53e5\u901a\u4fd7\u7684\u8bdd\u6765\u5f62\u5bb9\uff0cPEP-36\u5c31\u50cf\u662fTPEE\u52a0\u5de5\u8fc7\u7a0b\u4e2d\u7684\u201c\u4fdd\u9556\u201d\uff0c\u968f\u65f6\u51c6\u5907\u5316\u89e3\u5371\u673a\uff0c\u786e\u4fdd\u6750\u6599\u7684\u5b89\u5168\u4e0e\u5b8c\u6574\u3002<\/p>\n
\u4e3a\u4e86\u66f4\u597d\u5730\u7406\u89e3PEP-36\u7684\u529f\u80fd\u7279\u70b9\uff0c\u6211\u4eec\u9700\u8981\u5bf9\u5176\u4ea7\u54c1\u53c2\u6570\u8fdb\u884c\u8be6\u7ec6\u5206\u6790\u3002\u4ee5\u4e0b\u662fPEP-36\u7684\u4e3b\u8981\u6280\u672f\u6307\u6807\uff1a<\/p>\n\n\n\n\n\n\n\n\n\n\n
\u53c2\u6570\u540d\u79f0<\/th>\n | \u5355\u4f4d<\/th>\n | \u5178\u578b\u503c\u8303\u56f4<\/th>\n<\/tr>\n<\/thead>\n |
---|---|---|
\u5916\u89c2<\/td>\n | –<\/td>\n | \u6de1\u9ec4\u8272\u81f3\u7425\u73c0\u8272\u6db2\u4f53<\/td>\n<\/tr>\n |
\u5bc6\u5ea6<\/td>\n | g\/cm\u00b3<\/td>\n | 1.15-1.20<\/td>\n<\/tr>\n |
\u7c98\u5ea6\uff0825\u00b0C\uff09<\/td>\n | mPa\u00b7s<\/td>\n | 200-400<\/td>\n<\/tr>\n |
\u9178\u503c<\/td>\n | mg KOH\/g<\/td>\n | \u22641<\/td>\n<\/tr>\n |
\u78f7\u542b\u91cf<\/td>\n | %<\/td>\n | 10.0-11.0<\/td>\n<\/tr>\n |
\u84b8\u6c7d\u538b<\/td>\n | mmHg<\/td>\n | <0.1 @ 100\u00b0C<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n2.1 \u5916\u89c2\u4e0e\u7269\u7406\u6027\u8d28<\/h3>\nPEP-36\u901a\u5e38\u4ee5\u6db2\u6001\u5f62\u5f0f\u5b58\u5728\uff0c\u989c\u8272\u4ece\u6de1\u9ec4\u8272\u5230\u7425\u73c0\u8272\u4e0d\u7b49\u3002\u8fd9\u79cd\u5916\u89c2\u7279\u5f81\u662f\u7531\u5176\u5316\u5b66\u7ed3\u6784\u51b3\u5b9a\u7684\uff0c\u540c\u65f6\u4e5f\u8868\u660e\u5176\u7eaf\u5ea6\u8f83\u9ad8\u3002\u5176\u5bc6\u5ea6\u7ea6\u4e3a1.15-1.20 g\/cm\u00b3\uff0c\u7c98\u5ea6\u9002\u4e2d\uff0c\u4fbf\u4e8e\u6dfb\u52a0\u5230\u5404\u79cd\u805a\u5408\u7269\u4f53\u7cfb\u4e2d\u3002<\/p>\n 2.2 \u5316\u5b66\u6027\u8d28<\/h3>\nPEP-36\u7684\u6838\u5fc3\u6210\u5206\u662f\u4e9a\u78f7\u9178\u916f\uff0c\u5176\u4e2d\u78f7\u5143\u7d20\u7684\u542b\u91cf\u7ea6\u4e3a10%-11%\u3002\u8fd9\u4e00\u6bd4\u4f8b\u4fdd\u8bc1\u4e86\u5176\u5177\u6709\u8db3\u591f\u7684\u6d3b\u6027\uff0c\u53ef\u4ee5\u9ad8\u6548\u5730\u6355\u83b7\u81ea\u7531\u57fa\u5e76\u5206\u89e3\u8fc7\u6c27\u5316\u7269\u3002\u6b64\u5916\uff0c\u5176\u9178\u503c\u6781\u4f4e\uff08\u22641 mg KOH\/g\uff09\uff0c\u4e0d\u4f1a\u5bf9\u805a\u5408\u7269\u57fa\u6750\u4ea7\u751f\u8150\u8680\u4f5c\u7528\u3002<\/p>\n 2.3 \u70ed\u7a33\u5b9a\u6027<\/h3>\nPEP-36\u7684\u84b8\u6c7d\u538b\u4f4e\u4e8e0.1 mmHg\uff08100\u00b0C\u6761\u4ef6\u4e0b\uff09\uff0c\u8fd9\u610f\u5473\u7740\u5373\u4f7f\u5728\u9ad8\u6e29\u73af\u5883\u4e2d\uff0c\u5b83\u4e5f\u5f88\u96be\u6325\u53d1\u6216\u5206\u89e3\u3002\u8fd9\u79cd\u4f18\u5f02\u7684\u70ed\u7a33\u5b9a\u6027\u4f7f\u5f97PEP-36\u6210\u4e3a\u9ad8\u6e29\u52a0\u5de5\u9886\u57df\u7684\u7406\u60f3\u9009\u62e9\u3002<\/p>\n \n \u7b2c\u4e09\u7ae0\uff1aPEP-36\u7684\u4f5c\u7528\u673a\u5236\u89e3\u6790<\/h2>\n3.1 \u81ea\u7531\u57fa\u6355\u83b7<\/h3>\n\u5728TPEE\u52a0\u5de5\u8fc7\u7a0b\u4e2d\uff0c\u7531\u4e8e\u9ad8\u6e29\u548c\u6c27\u6c14\u7684\u5b58\u5728\uff0c\u6750\u6599\u5185\u90e8\u4f1a\u4ea7\u751f\u5927\u91cf\u7684\u81ea\u7531\u57fa\u3002\u8fd9\u4e9b\u81ea\u7531\u57fa\u4f1a\u653b\u51fb\u805a\u5408\u7269\u4e3b\u94fe\uff0c\u5bfc\u81f4\u65ad\u94fe\u548c\u4ea4\u8054\u53cd\u5e94\u7684\u53d1\u751f\u3002PEP-36\u901a\u8fc7\u63d0\u4f9b\u7535\u5b50\u7684\u65b9\u5f0f\uff0c\u8fc5\u901f\u6355\u83b7\u8fd9\u4e9b\u81ea\u7531\u57fa\uff0c\u5c06\u5176\u8f6c\u5316\u4e3a\u7a33\u5b9a\u7684\u5316\u5408\u7269\uff0c\u4ece\u800c\u7ec8\u6b62\u94fe\u5f0f\u53cd\u5e94\u3002<\/p>\n 3.2 \u8fc7\u6c27\u5316\u7269\u5206\u89e3<\/h3>\n\u9664\u4e86\u6355\u83b7\u81ea\u7531\u57fa\u5916\uff0cPEP-36\u8fd8\u80fd\u591f\u5206\u89e3\u7531\u6c27\u5316\u53cd\u5e94\u751f\u6210\u7684\u8fc7\u6c27\u5316\u7269\u3002\u8fc7\u6c27\u5316\u7269\u662f\u4e00\u79cd\u975e\u5e38\u6d3b\u8dc3\u7684\u4e2d\u95f4\u4ea7\u7269\uff0c\u5982\u679c\u4e0d\u80fd\u53ca\u65f6\u5904\u7406\uff0c\u53ef\u80fd\u4f1a\u5f15\u53d1\u66f4\u591a\u7684\u81ea\u7531\u57fa\u53cd\u5e94\u3002PEP-36\u901a\u8fc7\u4e0e\u8fc7\u6c27\u5316\u7269\u53d1\u751f\u53cd\u5e94\uff0c\u751f\u6210\u8f83\u4e3a\u7a33\u5b9a\u7684\u526f\u4ea7\u7269\uff0c\u4ece\u800c\u964d\u4f4e\u5176\u5bf9\u805a\u5408\u7269\u7684\u7834\u574f\u4f5c\u7528\u3002<\/p>\n 3.3 \u534f\u540c\u6548\u5e94<\/h3>\n\u5728\u5b9e\u9645\u5e94\u7528\u4e2d\uff0cPEP-36\u901a\u5e38\u4e0e\u5176\u4ed6\u6297\u6c27\u5316\u5242\uff08\u5982\u4e3b\u6297\u6c27\u52421010\u6216168\uff09\u5171\u540c\u4f7f\u7528\u3002\u7814\u7a76\u8868\u660e\uff0c\u8fd9\u79cd\u7ec4\u5408\u53ef\u4ee5\u4ea7\u751f\u663e\u8457\u7684\u534f\u540c\u6548\u5e94\uff0c\u4f7f\u6574\u4f53\u9632\u62a4\u6548\u679c\u8fdc\u8d85\u5355\u4e00\u7ec4\u5206\u7684\u8868\u73b0\u3002\u4f8b\u5982\uff0cPEP-36\u4e0e\u4e3b\u6297\u6c27\u52421010\u7684\u914d\u5408\u4f7f\u7528\uff0c\u53ef\u4ee5\u4f7fTPEE\u7684\u70ed\u6c27\u7a33\u5b9a\u6027\u63d0\u9ad830%\u4ee5\u4e0a\uff08\u6765\u6e90\uff1a\u300aPolymer Degradation and Stability\u300b\uff0c2015\u5e74\uff09\u3002<\/p>\n \n \u7b2c\u56db\u7ae0\uff1aPEP-36\u7684\u5e94\u7528\u573a\u666f\u4e0e\u6848\u4f8b\u5206\u6790<\/h2>\n4.1 \u6c7d\u8f66\u5de5\u4e1a<\/h3>\n\u5728\u6c7d\u8f66\u5236\u9020\u9886\u57df\uff0cTPEE\u88ab\u5e7f\u6cdb\u7528\u4e8e\u751f\u4ea7\u6cb9\u7ba1\u3001\u6c14\u56ca\u7ec4\u4ef6\u548c\u4f20\u52a8\u5e26\u7b49\u5173\u952e\u90e8\u4ef6\u3002\u8fd9\u4e9b\u90e8\u4ef6\u9700\u8981\u627f\u53d7\u9ad8\u6e29\u9ad8\u538b\u7684\u5de5\u4f5c\u73af\u5883\uff0c\u56e0\u6b64\u5bf9\u6750\u6599\u7684\u7a33\u5b9a\u6027\u8981\u6c42\u6781\u9ad8\u3002\u901a\u8fc7\u6dfb\u52a0PEP-36\uff0c\u53ef\u4ee5\u6709\u6548\u9632\u6b62TPEE\u5728\u52a0\u5de5\u8fc7\u7a0b\u4e2d\u51fa\u73b0\u964d\u89e3\u95ee\u9898\uff0c\u4ece\u800c\u4fdd\u8bc1\u7ec8\u4ea7\u54c1\u7684\u8d28\u91cf\u548c\u53ef\u9760\u6027\u3002<\/p>\n 4.2 \u5de5\u4e1a\u8bbe\u5907<\/h3>\n\u5728\u5de5\u4e1a\u8bbe\u5907\u4e2d\uff0cTPEE\u5e38\u7528\u4e8e\u5236\u9020\u5bc6\u5c01\u5708\u3001\u8f74\u627f\u548c\u5176\u4ed6\u8010\u78e8\u4ef6\u3002\u8fd9\u4e9b\u90e8\u4ef6\u7684\u4f7f\u7528\u5bff\u547d\u76f4\u63a5\u5173\u7cfb\u5230\u8bbe\u5907\u7684\u6574\u4f53\u6027\u80fd\u3002\u5b9e\u9a8c\u6570\u636e\u663e\u793a\uff0c\u7ecf\u8fc7PEP-36\u6539\u6027\u7684TPEE\uff0c\u5176\u8010\u78e8\u6027\u548c\u6297\u75b2\u52b3\u6027\u80fd\u53ef\u63d0\u534720%\u4ee5\u4e0a\uff08\u6765\u6e90\uff1a\u300aJournal of Applied Polymer Science\u300b\uff0c2017\u5e74\uff09\u3002<\/p>\n 4.3 \u8fd0\u52a8\u5668\u6750<\/h3>\n\u5bf9\u4e8e\u8fd0\u52a8\u978b\u5e95\u3001\u6ed1\u96ea\u677f\u7b49\u8fd0\u52a8\u5668\u6750\u800c\u8a00\uff0cTPEE\u7684\u67d4\u97e7\u6027\u548c\u56de\u5f39\u6027\u81f3\u5173\u91cd\u8981\u3002\u7136\u800c\uff0c\u957f\u65f6\u95f4\u66b4\u9732\u5728\u9633\u5149\u4e0b\u4f1a\u5bfc\u81f4\u6750\u6599\u8001\u5316\u53d8\u8106\u3002\u901a\u8fc7\u5f15\u5165PEP-36\uff0c\u4e0d\u4ec5\u53ef\u4ee5\u5ef6\u7f13\u8001\u5316\u8fc7\u7a0b\uff0c\u8fd8\u80fd\u4fdd\u6301\u6750\u6599\u539f\u6709\u7684\u4f18\u826f\u6027\u80fd\u3002<\/p>\n \n \u7b2c\u4e94\u7ae0\uff1a\u56fd\u5185\u5916\u7814\u7a76\u8fdb\u5c55\u4e0e\u5c55\u671b<\/h2>\n\u8fd1\u5e74\u6765\uff0c\u5173\u4e8ePEP-36\u7684\u7814\u7a76\u53d6\u5f97\u4e86\u8bb8\u591a\u91cd\u8981\u6210\u679c\u3002\u4f8b\u5982\uff0c\u4e2d\u56fd\u79d1\u5b66\u9662\u5316\u5b66\u7814\u7a76\u6240\u7684\u4e00\u9879\u7814\u7a76\u8868\u660e\uff0cPEP-36\u4e0e\u7eb3\u7c73\u4e8c\u6c27\u5316\u7845\u590d\u5408\u4f7f\u7528\uff0c\u53ef\u4ee5\u5728\u4e0d\u5f71\u54cdTPEE\u900f\u660e\u5ea6\u7684\u524d\u63d0\u4e0b\uff0c\u5927\u5e45\u63d0\u9ad8\u5176\u6297\u7d2b\u5916\u8001\u5316\u6027\u80fd\uff08\u6765\u6e90\uff1a\u300aChinese Journal of Polymer Science\u300b\uff0c2019\u5e74\uff09\u3002\u800c\u5728\u56fd\u5916\uff0c\u5fb7\u56fd\u62dc\u8033\u516c\u53f8\u5f00\u53d1\u4e86\u4e00\u79cd\u65b0\u578bPEP-36\u884d\u751f\u7269\uff0c\u5176\u6297\u6c27\u5316\u6548\u7387\u6bd4\u4f20\u7edf\u4ea7\u54c1\u9ad8\u51fa50%\u4ee5\u4e0a\uff08\u6765\u6e90\uff1a\u300aMacromolecular Materials and Engineering\u300b\uff0c2020\u5e74\uff09\u3002<\/p>\n \u672a\u6765\uff0c\u968f\u7740\u7eff\u8272\u5316\u5de5\u7406\u5ff5\u7684\u63a8\u5e7f\uff0c\u4eba\u4eec\u5bf9\u73af\u4fdd\u578b\u8f85\u6297\u6c27\u5242\u7684\u9700\u6c42\u5c06\u65e5\u76ca\u589e\u957f\u3002\u5728\u6b64\u80cc\u666f\u4e0b\uff0cPEP-36\u7684\u7814\u53d1\u65b9\u5411\u53ef\u80fd\u5411\u4ee5\u4e0b\u51e0\u4e2a\u65b9\u9762\u503e\u659c\uff1a<\/p>\n
|